Reactivity Series Flashcards
ELEMENT // COMPOUND COLOUR IS DIFFERENT!!!
H+ in reactivity series represent
acid
which 4 Reactivity Series metals react w/ water? + eqn
Potassium, Sodium, Calcium, Magnesium
metal + H2o -> metal hydroxide + H2
i.e. 2K(s) + 2H2o(l) -> 2KOH(aq) + H2(g)
https://docs.google.com/document/d/1Ep_FO9CxYSFbxmf3Zqg9mgm9NNyt2enpfMDr49gufrU/edit?tab=t.0 page 14
which reactivity series metals react w/ steam + eqn
Magnesium, Aluminium, Zinc… Iron
metal + steam -> metal oxide + H2
Potassium, Sodium, Calcium
can react, 2 dangerous
i.e. Zn(s) + H2o(g) -> ZnO(s) + H2(g)
https://docs.google.com/document/d/1Ep_FO9CxYSFbxmf3Zqg9mgm9NNyt2enpfMDr49gufrU/edit?tab=t.0 page 14
define displacement in metals
more reactive metal
displaces less reactive metal from
salt soln
displacement experiement setup
https://docs.google.com/document/d/1Ep_FO9CxYSFbxmf3Zqg9mgm9NNyt2enpfMDr49gufrU/edit?tab=t.0 page 13
why aluminium removed from reactivity series?
has protective layer (Al2O3)
- Al react readily w/ Oxygen
- will not show reactivity immediately
even tho it is high up enf in reactivity series such dat it will react w/ acid
it has protective layer
why aluminium used, food wrapper?
has protective layer (Al2O3)
- will not rust
how cause aluminium react?
- scrape, sandpaper
- Place into acid, long time
- AlO -> amphotheric, will react w/ acid, long period time
https://docs.google.com/document/d/1Ep_FO9CxYSFbxmf3Zqg9mgm9NNyt2enpfMDr49gufrU/edit?tab=t.0 page 15
G1 metals/K, Na, Ca displacement why dont use/why bubbling?
- Soln G1 metal placed in, (aq)
- Sodium react w/ water violently, high reactivity
thermal decomposition
which metal easier decompose?
Less reactive metal, easier metal carbonate decompose
sulfate, nitrate, carbonate also decompose
not only carbonate
Why Potassium, Sodium, G1 metals formed compounds nvr thermally decompose
no reaction
1. K, Na vry reactive
2. (other anion) thermally stable
3. bonds formed vry strong
4. req lot of heat energy, break
5. G1 metals dont thermally decompose
- K, Na bonds super strong coz vry reactive.
- It desperately clings onto other anion
- ionic bonds dosent end up breaking and thermally decomposing
sulfate, nitrate, carbonate also decompose
not only carbonate
- CaO (s) + C(s) ->
- 2CuO (s) + C (s) ->
- reduction by carbon reaction does not happen, C less reactive, Ca
- reduction happens (Co2 (g) + 2Cu (s)), C more reactive, Cu
works the same way, displacement does.
C (s) is always the displacer.
**eqn: ** metal oxide + carbon -> co2 + 2cu(s)
- CaO (s) + H2 (g) ->
- CuO + H2 (g) ->
- reduction by hydrogen gas does not happen, H2 less reactive, Ca
- reduction happens (H2o (g) + 2Cu (s)), H2 more reactive, Cu
works the same way, displacement does.
H2 (g) is always the displacer.
**eqn: ** metal oxide + h2 -> h2o(l) + metal
does silver carbonate decompose?
yez
1. decompose, silver oxide Ag2O + co2
- 2Ag2o unstable, decompose further -> 4Ag + o2
.
reactivity series
list out all metals that thermally decompose
form what products?
all except potassium, sodium
carbonate decomposes, form metal oxide + co2
metal carbonate -> metal oxide + carbon dioxide
top 4 reactive metals in reactivity series…
1. desc how react in water
Potassium: explosive, (giving out bright flame)
Sodium: fast
Calcium: readily
Magnesium: slow
how determine state symbols if not given
- look for struct
- i.e. SMS = low mp, bp, (g)
- i.e. GILS = high mp, bp (s)
metal coating
vs
sacrificial protection
advantage, disadvantage
metal coating:
nicer finish (aesthetics)
small hole for h2o, o2 enter, ineffective
sacrificial protection:
no need coat entire surface, need replace metal once in a while
uses of stainless steel, mild steel, aluminium
stainless: surgical instruments/ stainless steel cutlery
mild: car bodies/machinery
aluminium: soft drink cans
what does acid rain do?
acid rain
1. corrode limestone struct, metal
2. kill aquatic life (acidic rivers)
does industry commonly use pure metal? if not wat use?
no
use alloy
iron react w/ steam eqn is…? (unique pt)
reversible
3Fe (s) + 4h2o (g) -> Fe3O4 + 4H2 (g)
iron and steam
fe3o4 is unique, containing both iron (II) and (III) ions
iron rusting
fe2o3 (iron III)
reduction, metal, C eqn
metal oxide + carbon -> Co2 (g) + metal
metal BELOW C reduce
For extraction of pure metal
Metal is reduced.
reduction, metal, H2 eqn
metal oxide + H2 (g) -> metal + water vapour
metal BELOW H+ reduce
For extraction of pure metal
Metal is reduced.
Y reactive metal greater tendency displace less reactive metal
- more reactive metal, greater tendency lose electrons
- than less reactive metal
- forming cations
explain sacrificial protection
- more reactive metal attach less reactive metal
- more reactive metal oxidise, corrode first
- e.g. zinc bars on hull on steel ships
- replace regularly
- less exp, replace entire steel struct
explain galvanising
coating less reactive metal w/ zinc
type of sacrificial protection
coating dmg -> still sacrificial protection
explain use alloys prevent rusting method
contain Nickel, Chromium, rust-resistant alloys i.e. stainless steel
Ni, Cr cause Fe to not rust easily in stainless steel
only iron rust.
use protective layer prevent rust/oxidation
- apply coat, paint
- oil: machinery parts
- metal coating: food cans
- plastic coating: kitchenware
what happens, rusting of iron
slow oxidation + exposed 2 water, oxygen in air,
iron, form hydrated iron(III) oxide (rust)
define rust
flaky red-brown substance
rusting of iron chem formula
4Fe + 3O2 + 2xH2o -> 2Fe2O3.xH2o (s)
iron + oxygen + water -> hydrated iron (III) oxide
what increases rate of rusting
presence of sodium chloride
which metals extracted by what method
electrolysis, molten ore: PSCMA
heating metal oxide w/ carbon // reduction w/ carbon: ZITLHCS
physical methods: GT
ore
compounds, metals
mixed w/ earth, rocks
which metals rust?
ONLY IRON
rest corrode/oxidise
after CuO reduced by H2 (g) in a hot env.,
H2 (g) is continuously allowed to flow through until surrounding temp cools down
why is that so?
prevent copper (II) react w/ H2o (g) in air forming CuO again
as temp is high enf, reaction w/ moisture in air to occur
what is magnesium fuse for in displacement reaction
provide energy,
displacement reaction
atomic size means…
atomic radii
reduction need heat?
SOME
need heat energy, reduce metal oxide -> metal
metal another state besides (s)
molten state
(l)
only if stated.