Properties of Period 3 elements and their oxides Flashcards
What is the equation for sodiums reaction with water
2Na + 2H2O —> 2NaOH + H2
What is the equation for magnesium’s reaction with water (cold)
Mg + 2H2O —> Mg(OH)2 + H2
What is the equation for magnesium’s reaction with steam
Mg + H2O —> MgO + H2
What is the equation for magnesium’s reaction with oxygen?
2Mg + O2 —> 2MgO
What is the equation for aluminiums reaction with oxygen?
4Al + 3O2 —> 2Al2O3
What is the equation for sodiums reaction with oxygen?
4Na + O2 —> 2Na2O
What is the equation for silicons reaction with oxygen?
Si + O2 —> SiO2
What is the equation for phosphorous’s reaction with oxygen?
4P + 5O2 —> P4O10
What are the equations for sulphurs reaction with oxygen?
S + O2 —> SO2
2SO2 + O2 —> 2SO3
How does melting point change of the oxides from Na2O —> SO3
The giant structures (the metal oxides and silicon dioxide) have high boiling points due to strong ionic and covalent bonds
The non metals all form VDW forces so have low Mp’s and Bp’s
What is the equation for sodium oxides reaction with water? What is the pH of the product formed?
Na2O + H2O —> 2NaOH
14
What is the equation for magnesium’s oxides reaction with water?
MgO + H2O —> Mg(OH)2
What is the equation for aluminium oxides reaction with water?
Aluminium oxide is insoluble in water
7
What is the equation for silicon oxides reaction with water?
Silicon dioxide is insoluble in water
7
What is the equation for phosphorous oxides reaction with water?
P4O10 + 6H2O —> 4H3PO4
H3PO4 ⇌ H+ + H2PO4- (dissociates to this in the water)
What is the equation for sulphur dioxides reaction with water?
SO2 + H2O —> H2SO3
H2SO3 ⇌ H+ + HSO3- (dissociates to this in the water)
2
What is the equation for sulphur trioxides reaction with water?
SO3 + H2O —> H2SO4
H2SO4 ⇌ H+ + HSO4- (dissociates to this in the water)
How does sodium oxide react with HCl
Na2O + 2HCl —> 2NaCl + H2O
How does magnesium oxide react with HCl
MgO + 2HCl —> MgCl2 + H2O
Why is aluminium oxide special
Its amphoteric
How does aluminium oxide react with HCl
Al2O3 + 6HCl —> 2AlCl3 + 3H20
How does aluminium oxide react with NaOH and H2O
Al2O3 + 2NaOH + 3H2O —> 2NaAl(OH)4
How does silicon dioxide react with NaOH
SiO2 + 2NaOH —> Na2SiO3 + H2O
How does phosphoric acid react with NaOH
H3PO4 + NaOH —> NaH2PO4 + H2O
NaH2PO4 + NaOH —> Na2HPO4 + H2O
Na2HPO4 + NaoH —> Na3PO4 + H2O
How does SO2 react with NaOH
SO2 + NaOH —> NaHSO3
NaHSO3 + NaOH —> Na2SO3 + H2O
How does sulphur trioxide react with NaOH
SO3 + 2NaOH —> Na2SO4 +H2O
How does aluminium oxide react with H2SO4
Al2O3 + 3H2SO4 —> Al2(SO4)3 + 3H2O
SO4 = 2-
Al = 3+ but x2
Therefore 3 sulphates needed
How to tell the difference between aqueous SO2 and aqueous SO3
Universal indicator
SO2 orange red
SO3 red
CaCO3
SO2 slower effervesce
SO3 faster effervesce
How does aluminium oxide react with NaOH
Al2O3 + 2NaOH —-> 2NaAlO2 + H2O
Formula and charge of phosphate ion
PO4 3-
Formula and charge of an aluminate ion
Al(OH)4 1-
Formula and charge of silicate ion
SiO3 2-