Production of chemicals using electrolysis Flashcards
Anode
electrode where oxidation (loss of electrons) occurs
Aqueous electrolyte
dissolved ionic compound with ions that are free to move (in aqueous state)
Cathode
electrode where reduction (gain of electrons) occurs
Electrolytic half-equation
one of two equations (oxidation or reduction) that describes one half of an electrolytic reaction
Electrolytic reaction
non-spontaneous redox reaction that requires a specified voltage from an external power source to occur
Molten electrolyte
melted ionic compound with ions that are free to move (in liquid state)
Additive
a substance added to improve or optimise a chemical process
Electrolytic cell
cell that facilitates electrolytic (non-spontaneous redox) reactions
Electroplating
application of a layer of a metal onto another metal during an electrolytic reaction
Polarity (in electrochemical cells)
overall charge of an electrode
Standard electrode potential (E 0)
potential of a half-cell reaction, given in volts (V), relative to the Standard Hydrogen Electrode
Battery
device consisting of cells that convert chemical energy into electrical energy
Discharge
conversion of chemical energy into electrical energy as a result of spontaneous redox reactions
Recharge
conversion of electrical energy into chemical energy through electrolytic reactions
Secondary cell
electrochemical cell that can be recharged
Artificial photosynthesis
process that utilises human-made materials to capture sunlight and split water molecules to create hydrogen and oxygen
Electrolyser
a device or system that houses the process of electrolysis and manages the process flow of inputs and outputs
Green hydrogen
hydrogen gas produced using renewable energy sources, such as wind or solar power, through electrolysis
Photovoltaics
conversion of solar energy to electrical energy using human-made materials
Polymer electrolyte membrane (PEM)
also called proton exchange membrane, uses a proton-conducting polymer membrane as the electrolyte and connects two half-cells, but prevents the mixing of different molecules
Coulomb
unit of electric charge (equal to the quantity of charge carried by a current of 1 ampere in 1 second)
Electric charge
property of matter carried by current and measured in coulombs where the charge on a single electron is -1.60 x 10^-19 coulombs
Faraday constant (F)
charge on one mole of charged particles, equal to 96 500 coulombs per mole