polymerisation Flashcards

1
Q

what si a polyester

A

it has an ester monomer repeated over and over - joined by condensation reactions

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2
Q

how is an amide formed

A

when a carboxylic acid and amine join

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3
Q

why is kevlar so strong

A

rigid chains and the ability of the planar benzene to pack together held together by vdw foa.

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4
Q

why are polyethene and polypropene not biodegradable

A

they have strong non-polar C-H and C-C bonds. there is nothing in the natural environment that will easily break them down

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5
Q

why do amino acids have high melting points

A

they are ionic - within their zwitterion there is a strong dipole therefore strong electrostatic forces of attraction

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6
Q

can amino acids dissolve in water

A

yes - but VERY poorly in non-polar solvents

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7
Q

how will an amino acid behave in strongly acidic conditions

A

the lone pair on the NH2 will become protonated

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8
Q

how will an amino acid behave in strongly alkaline conditions

A

the OH- looses a proton
the carboxylic group becomes deprotonated

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9
Q

which amino acid shows optical isomerism

A

alanine

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10
Q

how can an amino acid display optical isomerism

A

there is an equal possibility of attack above an below the plane of c=o. plane polarised light is able to rotate in an equal ration to show no change in the racemic mixture.

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11
Q

what does an acid and a base make

A

a salt and water

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12
Q

what is the functional group of an ester

A

coo

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13
Q

what is a plasticizer

A

allows compounds to become more flexible - the ester will push polymers apart and weaken bond s

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14
Q

what are common uses of esters

A

perfumes, food flavouring, solvents AND plasticisers

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15
Q

di esters have a high or low bpt

A

low

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16
Q

what is the density of esters like

A

less dense than water

17
Q

are esters immiscible

A

yes

18
Q

what are the products when an ester is hydrolysed with HCl

A

carboxylic acid and alcohol

19
Q

what are the products when an ester is hydrolysed with NaCl

A

carboxylate salt and an alcohol

20
Q

what type of esters are fats and oils

A

tri-esters

21
Q

how many fatty acids do glycerol have

A

3

22
Q

why are fatty acids insoluble

A

they have massive r groups - water can not get in and dissolve the fatty acid. the fatty acids are non polar and the predominant foa is vdw

23
Q

what are the intermolecular foa between fatty acids

A

there is a lot of contact between molecule so the IFOA is strong

24
Q

what is the strength like in an unsaturated fatty acid

A

weak - they cannot get close - vdw is weak