alcohols Flashcards

1
Q

what does a primary alcohol oxidise into

A

aldehyde

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2
Q

what does a secondary alcohol oxidise into

A

ketone

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3
Q

what does a tertiary alcohol oxidise into

A

does not oxidise because there is no hydrogen for it to oxidise with

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4
Q

what are the three definition of oxidation

A

loss of electrons
loss of hydrogen
gain of o2

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5
Q

what are the three definitions of reduction

A

gain of electrons
gain of hydrogen
loss of o2

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6
Q

what happens when you dont immediately distil off a primary alcohol

A

it will turn straight into a carboxylic acid and miss out the aldehyde step

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7
Q

define a base

A

proton acceptor

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8
Q

what does acid + alkali =

A

salt and water

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9
Q

why should dichromate handled with care

A

dichromate is a carcinogen = toxic

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10
Q

how can aldehydes and ketones be turned back into alcohols

A

a strong reducing agent

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11
Q

how to turn a alcohol to an alkene

A

conc h2so4 or h3po4 (dehydrating agent)
under warm reflux

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12
Q

how can an acid catalyse a reaction

A

by protonating a carbonyl group

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13
Q

how can an alkali catalyse a reaction

A

by deprotonating an alcohol

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14
Q

how can glucose be turned into ethanol

A

in the absence of air yeast will catalyse the production of ethanol and carbon dioxide from glucose.
conditions - at 35-55 degrees

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15
Q

what are some advs to fermentation reactipn

A

cheap
renewable becausr the glucose comes from sugar cane (plant)
low tech
can be done pretty much anywhere
low energy

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16
Q

what are some dadv to fermentation

A

slow process

17
Q

what does a metal and a carbonate make

A

h2o +co2 +salt

18
Q

describe the process of fermentation

A

an exothermic reaction
carried out by yeast in anaerobic conditions

C6H12O6 (aq)———-> 2C2H5OH(aq) +2CO2(g)

yeast is the catalyst at 30-40 degrees

19
Q

define carbon neutral

A

no net release of carbon

20
Q

what is an advantage of biofuel

A

renewable energy source
most biofuels are considered carbon neutral

21
Q

what are some dadvs or biofuel

A

using land to grow the crops that will just be burned and not using the space for growing food
- deforestation
- destruction of habitats to grow plants = decrease in biodiversity

22
Q

give the equations to show that ethanol is a carbon neutral fuel source

A

6CO2 +6H2O—–> C6H12O6 + 6O2
C6H12O6 —–>2C2H5OH +2CO2
2C2H5OH +6O2 —–> 4CO2 +6H2O

across these three equations six molecules of carbon dioxide went in and 2+4 came out

23
Q

why might some people not think ethanol is carbon neutral

A

to power the machinery to farm the crops. refining and transporting the bioethanol also uses energy.