acid Flashcards

1
Q

what is a brownstead-lowry acid

A

an acid that can donate a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is a brownstead-lowry base

A

a substance that can accept a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what si the equation between acid ands base reactions h2so4 and hno3

A

H2SO4 +HNO3 ——–> H2NO3+ + HSO4-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what is the value of Kw

A

1.0x10-14

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

what will make a solution more acidic

A

a higher charge density that will polarise and cause more electrons to be withdrawn and therefore more H+ will dissociate = more acidic

longer alkyl group the more electrons there is to loose = more H+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is a conjugate acid

A

a species that gains a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is a conjugate base

A

a species that looses a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is the equation for pH

A

pH= -log10(H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what is the equation for H+ if pH is known

A

H+ = 10 ^-pH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

define Kw

A

it is the resulting equilibrium constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

equation of (H+)
using Kw and OH-

A

Kw/OH-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

which type of acids is Ka used for

A

weak

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is the equation for Ka

A

Ka = (H+)(A-)/(HA)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

REMEMBER

A

(H+)=(A-)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is pKa used for

A

a scale used to determine the rekative strength of a weak acid

the higher the pKa the weaker the acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is the eqaition for pKa

A

pKa = -log10Ka

7
Q

what is the pH of a strong acid weak base

A

pH<7

8
Q

define an equivalence point

A

point where pH is changing is changing most rapidly - it occurs when (H+)=(OH-)

9
Q

where must pH range be within for indicators to be effective

A

the equivalence point - at the inflection

10
Q

which pH will neutralistaion of salts occur at

A

slightly higher than norm because the salt accepts loads of OH-

11
Q

what is a buffer formed from

A

a weak acid and a salt of the weak acid

12
Q

what are assumptions made when a buffer solution is made

A

the source of salt in the weak acid acid salt comes from the added salt - this will ignore any dissociation of the weak any dissociation

  • the concentration of the weak acid is the same concentration of the weak acid at equilibrium
13
Q

what does the strength of a base depend upon

A
  • how readily thry can accept a proton
    – alkyl chains which release electrons in a negative inductive effect
14
Q

what is a zwitterion

A

ions that have both a permanent positive charge and a permanent negative charge

15
Q

what is an example of a zwitterion

A

amino acid