enthalpy definitions Flashcards

1
Q

define enthalpy chnage

A

the heat enrgy change help under a constant pressure

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2
Q

define enthalpy of formation

A

the enthalpy change when 1 mole of a substance is formed from it elements. aal products and reactants are held in standard conditions

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3
Q

define enthalpy of combustion

A

the enthalpy change when 1 mole of a substance is burned completely in oxygen. products and reactants must be in their standard states

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4
Q

is enthalpy of combustion endothermic or exothermic

A

exothermic

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5
Q

is enthalpy of formation endothermic or exothermic

A

exothermic

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6
Q

define enthalpy of neutralisation

A

enthalpy change when 1 mole of water is formed in a reaction between an acid and an alkali. all products and reactants must be in standard consitions

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7
Q

define first ionistation energy

A

the enthalpy required for 1 mole of electrons to be lost from a gaseous atom to form 1 mole of gaseous 1+ compound

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8
Q

define second ionisation enrgy

A

the enthalpy required to remove 1 mole of electrons from a gaseous 1+ ion to form a gaseous 2+ ion

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9
Q

define first electron affinity

A

enthalpy change when each atom in one mole of a gaseous gains one electron to form 1 mole of gaseous 1- ions

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10
Q

define second electron affinity

A

enthalpy change when each ion in one mole of a gaseous 1- ion gains an electron to form a gaseous 2- ion

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11
Q

define enthalpy of atomisation

A

enthalpy change when one mole of gaseous atoms are produced from an element in its standard state

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12
Q

is enthalpy of atomisation endothermic or exothermic

A

endothermic

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13
Q

define hydration enthalpy

A

enthalpy when 1 mole of gaseous ions ions become hydrated

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14
Q

is enthalpy of hydration endothermic or exothermic

A

exothermic

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15
Q

define enthalpy of solution

A

enthalpy change when 1 mole of ionic solid is completly dissolved to infinite dilution

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16
Q

define infinite dilution

A

that substances have no exertion on other substances. the ions will not interact with each other

17
Q

define bond dissociation energy

A

enthalpy change required to break 1 mole of bonds in a gaseous substance

18
Q

define lattice enthalpy of formation

A

enthalpy change when 1 mole of solid ionic compound is formed from its constituent ions in the gas state

exothermic

19
Q

define lattice enthalpy of dissociation

A

enthalpy change when one mole of a solid ionic compound is broken into its constituent ions in the gas phase

endothermic

20
Q

define enthalpy of vaporisation

A

enthalpy change when one mole of liquid is turned to gas

exotheric

21
Q

define enthalpy of fusion

A

enthalpy change when one mole of solid is turned to liquid

endothermic

22
Q

what is the biggest factor affecting enthalpy of atomistaion

A

CHARGE

BUT shielding is still a factor