enthalpy definitions Flashcards
define enthalpy chnage
the heat enrgy change help under a constant pressure
define enthalpy of formation
the enthalpy change when 1 mole of a substance is formed from it elements. aal products and reactants are held in standard conditions
define enthalpy of combustion
the enthalpy change when 1 mole of a substance is burned completely in oxygen. products and reactants must be in their standard states
is enthalpy of combustion endothermic or exothermic
exothermic
is enthalpy of formation endothermic or exothermic
exothermic
define enthalpy of neutralisation
enthalpy change when 1 mole of water is formed in a reaction between an acid and an alkali. all products and reactants must be in standard consitions
define first ionistation energy
the enthalpy required for 1 mole of electrons to be lost from a gaseous atom to form 1 mole of gaseous 1+ compound
define second ionisation enrgy
the enthalpy required to remove 1 mole of electrons from a gaseous 1+ ion to form a gaseous 2+ ion
define first electron affinity
enthalpy change when each atom in one mole of a gaseous gains one electron to form 1 mole of gaseous 1- ions
define second electron affinity
enthalpy change when each ion in one mole of a gaseous 1- ion gains an electron to form a gaseous 2- ion
define enthalpy of atomisation
enthalpy change when one mole of gaseous atoms are produced from an element in its standard state
is enthalpy of atomisation endothermic or exothermic
endothermic
define hydration enthalpy
enthalpy when 1 mole of gaseous ions ions become hydrated
is enthalpy of hydration endothermic or exothermic
exothermic
define enthalpy of solution
enthalpy change when 1 mole of ionic solid is completly dissolved to infinite dilution
define infinite dilution
that substances have no exertion on other substances. the ions will not interact with each other
define bond dissociation energy
enthalpy change required to break 1 mole of bonds in a gaseous substance
define lattice enthalpy of formation
enthalpy change when 1 mole of solid ionic compound is formed from its constituent ions in the gas state
exothermic
define lattice enthalpy of dissociation
enthalpy change when one mole of a solid ionic compound is broken into its constituent ions in the gas phase
endothermic
define enthalpy of vaporisation
enthalpy change when one mole of liquid is turned to gas
exotheric
define enthalpy of fusion
enthalpy change when one mole of solid is turned to liquid
endothermic
what is the biggest factor affecting enthalpy of atomistaion
CHARGE
BUT shielding is still a factor