Electron configuration Flashcards
what is the formula for the main energy level
2n^2
where n is the number of the energy level so the first energy level holds two electrons the second holds 8
do the shapes of the electrons in the s d and p orbitals effect the shape of the molecule
why
yes
they represent a volume of space in which there is a 95% probability of finding an electron
what is the max amount of electrons any single atomic orbital can hold
2
how many groups do s-orbitals have
just one so there is still only 2 electrons
how many groups do p orbitals have
3 (still 2 electrons in each orbital) so in these 3 groups that will carry the same energy there will be 6 electrons in the p orbital
how many groups do the d orbitals have
5, each with the 2 electrons in the orbital of the same energy to give 10 in the d-sub level
note
in the orbital the electrons are a pair that are of the same negative charge so will try to move as far as possible from one another and this adds to the specific shape of the molecule
what is ionisation energy
the energy required to remove 1 mole of electrons from 1 mole of an atom in a gaseous state and is measured in KJmol-1
whta happens as a result of atoms being ionised
atoms become positive ions - cations
why is the first ionisation energy always the lowest
because it is being removed from a neutral atom - no electrons ahve been removed before
why is the second and so on ionisation energies higher than the first
because now you are removing electrons from a positive ion with charge it will now have a greater electrostatic force of attraction to the nucleus - it gains a successive ionisation energy as more electrons are removed because more energy will be required
what is the trend of ionisation energies on the periodic table
- increases across a period because of an increase in nuclear charge from the protons and neutrons which will make it more difficult to remove an electron and requires more enrgy
- increases up the group because the electrons are closer to the nucleus so the nuclear force of attraction is stronger
explain the decrease in first ionisation nergy between Mg- Al
the p orbital is higher in energy than the s orbital ( it is furtehr away from the nucleus