Periodicity- Ionisation Energies 3.7.2 Flashcards
first ionisation energy definition
The energy required to remove one electron from each atom in one mole of gaseous atoms
Na (g) -> Na+ (g) + e-
What factors affect ionisation energy?
Nuclear charge, Atomic radius and Shielding
What happens if there’s pairs in a sub level?
The paired electrons repel/push other electrons away making it easier to remove, decreasing the ionisation energy.
What happens to ionisation energy as you go up a group?
The IE increases - closer to nucleus, less shielding
What happens to ionisation energy across a period?
The nuclear charge increases as you across north the group and the atomic radius decreases, there is a greater attraction between the nucleus and outer electrons so IE would increase.
What is outweighed with first ionisation energies down a group?
Although nuclear charge increases its effect is outweighed by the increased radius and to a lesser extent, the increased shielding.