(Benzene) Synthetic Routes Chp 28 Flashcards
1
Q
Benzene to Nitrated benzene
A
Conc HNO3/Conc H2SO4 at 50-55C
2
Q
Nitrated benzene to NH2 benzene
A
Sn/HCl (reduction)
3
Q
NH2 benzene to brominated benzene with NH2
A
Br2
4
Q
Benzene to Brominated Benzene
A
Br2/ AlBr3 or FeBr3
5
Q
Benzene to Chlorinated Benzene
A
Cl2/ AlCl3 or FeCl3
6
Q
Benzene Acylation
A
CH3COCl/AlCl3 under reflux
7
Q
Benzene Alkylation
A
CH3Cl/AlCl3 under reflux
8
Q
Benzene w Carbonyl group to Alcohol
A
NaBH4 (reduction)
9
Q
Phenol to Brominated Phenol
A
Br2
10
Q
Phenol to Salt
A
NaOH (aq)
11
Q
Phenol nitration
A
dilute HNO3 (2,4 directing)