(Benzene) Synthetic Routes Chp 28 Flashcards

1
Q

Benzene to Nitrated benzene

A

Conc HNO3/Conc H2SO4 at 50-55C

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2
Q

Nitrated benzene to NH2 benzene

A

Sn/HCl (reduction)

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3
Q

NH2 benzene to brominated benzene with NH2

A

Br2

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4
Q

Benzene to Brominated Benzene

A

Br2/ AlBr3 or FeBr3

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5
Q

Benzene to Chlorinated Benzene

A

Cl2/ AlCl3 or FeCl3

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6
Q

Benzene Acylation

A

CH3COCl/AlCl3 under reflux

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7
Q

Benzene Alkylation

A

CH3Cl/AlCl3 under reflux

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8
Q

Benzene w Carbonyl group to Alcohol

A

NaBH4 (reduction)

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9
Q

Phenol to Brominated Phenol

A

Br2

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10
Q

Phenol to Salt

A

NaOH (aq)

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11
Q

Phenol nitration

A

dilute HNO3 (2,4 directing)

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