Periodic Table Trends Flashcards
Atomic radius
Half the distance between the nuclei in a molecule consisting of two identical atoms
Trends for atomic radii
Decreases going from left to right
Increases going down a group
Ionization energy
Energy required to remove an electron from an atom in its gaseous states
Why does the ionization energy increase as you keep on removing
The nucleus draws the electrons closer which makes the forces string which take more energy to remove
What happens when all valence electrons are removed
You have to remove a core electron and the ionization energy increases tremendously
Trends in ionization energy
Decreases as you go down a group: size of the orbital increase electrons move farther apart causes weaker attractions
Increases going left to right more strongly bound to nucleus as moving to the right
Exceptions from ionization trends
Decreases going from Be to B because electrons in the final 2s orbital provide some shielding for electrons in 2p orbital
Decrease in ionization going from nitrogen to oxygen: extra electron repulsion from doubly occupied p orbital
Electron affinity
Energy change associated with the addition of an electron to its gaseous state
Trends for electron affinity
Becomes more negative going from left to right across a period
Oxygen and electron affinity
The increase in oxygens nuclear number is sufficient to overcome the repulsion’s associated with putting a 2nd electrons into an already occupied 2p orbital