Hybridization Of Atomic Orbitals Flashcards

1
Q

Hybridization

A

Types of description for atomic orbitals used by atoms to share electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

How can molecules account for their exact nature

A

Adopting a set of atomic orbitals other than 2s or 2p

Mixing called hybridization

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Sp3 hybridization

A

One 2s orbitals and three 2p orbitals are combined to make four identical orbitals (4 bonding pairs —> 8 e-)
All 4 orbitals have the same shape
TETRAHEDRAL ARRANGEMENTS —> 109.5

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Degenerate

A

Same amount of energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What are the bonds sp3 hybridization leads to

A

4 sigma (single bonds) can take 4 extra electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Sp2 hybridization

A

Mixing of one 2s orbital and 2/3 2p orbitals

Each a set of 3 identical sigma bonds (can take 3e- extra)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Energy for sp2 orbitals

A

One extra p orbital is higher in energy than the rest

The extra p orbital is ready for a pi bond (double)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What is the secondary bound for sp2

A

Occurs by sharing one electrons above and below the sigma

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What does a double bond consist of

A

Of one sigma bond

One pi bond where one is below no one is above

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Sp hybridization

A

Mixing one s orbital with 1/3 p orbital
2 2p orbitals available for further bonding
2 sp orbitals forms single bonds
Extra 2p orbital form pi bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Geometry of sp hybridization

A

Provide linear 180

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Dsp3 hybridization

A

Mixing of one s obital, one d and 3 p

Accounts for the molecules that exceed the octet rule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Geometry of dsp3

A

Trigonal bipyrimidal angle 90 between x-y plane

120 between x-x plane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

D2sp3 hybridizations

A

Mixing one s, 3 p, 2d

Accounts for the molecules with 6e- pairs

How well did you know this?
1
Not at all
2
3
4
5
Perfectly