Hybridization Of Atomic Orbitals Flashcards
Hybridization
Types of description for atomic orbitals used by atoms to share electrons
How can molecules account for their exact nature
Adopting a set of atomic orbitals other than 2s or 2p
Mixing called hybridization
Sp3 hybridization
One 2s orbitals and three 2p orbitals are combined to make four identical orbitals (4 bonding pairs —> 8 e-)
All 4 orbitals have the same shape
TETRAHEDRAL ARRANGEMENTS —> 109.5
Degenerate
Same amount of energy
What are the bonds sp3 hybridization leads to
4 sigma (single bonds) can take 4 extra electrons
Sp2 hybridization
Mixing of one 2s orbital and 2/3 2p orbitals
Each a set of 3 identical sigma bonds (can take 3e- extra)
Energy for sp2 orbitals
One extra p orbital is higher in energy than the rest
The extra p orbital is ready for a pi bond (double)
What is the secondary bound for sp2
Occurs by sharing one electrons above and below the sigma
What does a double bond consist of
Of one sigma bond
One pi bond where one is below no one is above
Sp hybridization
Mixing one s orbital with 1/3 p orbital
2 2p orbitals available for further bonding
2 sp orbitals forms single bonds
Extra 2p orbital form pi bonds
Geometry of sp hybridization
Provide linear 180
Dsp3 hybridization
Mixing of one s obital, one d and 3 p
Accounts for the molecules that exceed the octet rule
Geometry of dsp3
Trigonal bipyrimidal angle 90 between x-y plane
120 between x-x plane
D2sp3 hybridizations
Mixing one s, 3 p, 2d
Accounts for the molecules with 6e- pairs