Bonding General Concepts Part II Flashcards
LEWIS STRUCTURE
Valence electron configuration of covalent compounds
What are the two types of electron pairs
Lone pairs —> not bonded
Bonding pairs —> bonded
What is the most important requirement for making compounds
The formation of a stable compound contains the configuration of a noble gas
Octet rule
Having eight valence electrons
Steps for writing Lewis structure
- Find the total number of valence electrons
- Use the one pair (one line) to form a bond between central and outer
- Arrange the remainder ass lone pairs on the outer atoms
- If no unassigned remains but central atom doesn’t have eight, created double or triple bond
What are the exceptions to octet rule
Atoms that lack electrons such as B and Be
Atoms that exceed S and P
Resonance
When there is more than one valid Lewis structure indicated by a double heade3d arrow
Why does resonance happen
Due to the declination of electrons meaning they are free to move around
Formal charge
In order to know which Lewis structure is the best
Difference between the number fo electrons on the free atom and the number of valence electrons assigned to the atom in the molecule
Formula for formal charge
of valence electron in free atom - 1/2bonding electrons-lone pairs
What are the two assumptions about formal charge for Lewis structure
Atoms try have a charge as close to zero as possible any negative formal charges are expected to reside on the most electronegative atom
What is the main theory of the VSEPR MODEL
Determined by minimizing electron pair repulsion’s
Molecules containing 2 bonds
Separation 180
Geometry linear
Molecules containing 3 bonds
Maximum separation 120
Geometry trigonal planar
Molecules contains 4 bonding
Angle 109.5
Tetrahedral