P2 - 8.4 Test for Anions Flashcards
Chemical Analysis
What is an anion
A negatively charged ion
What are the 3 tests we can do to test for anions
- Carbonate ion
- sulfate ion
- halide ion
What are the products of a carbonate reacting with an acid
Salt + carbon dioxide + water
What is the equation for carbonates reacting with acid
Carbonate + acid -> salt + carbon dioxide + water
What is the test for carbon dioxide
Bubbling carbon dioxide gas through lime water
If it turns cloudy then CO2 is present
What is the test for carbonates
Add dilute HCl (hydrochloric acid) to our test sample and take any gas produced ( if carbonate it should be CO2) and run it through limewater, if it turns cloudy it is a carbonate
What would be a positive test result for testing for carbonates
If the limewater turns cloudy it means carbon dioxide would have been produced which is a product of a carbonate and dilute hydrochloric acid (HCl) mixing together
What would be a positive test result for testing for carbon dioxide
Limewater turning cloudy
What would be a negative test result for testing for carbon dioxide
If the limewater did not turn cloudy it would mean there was no carbon dioxide
What would be a negative test result for testing for carbonates
If the limewater did not turn cloudy then that would mean no CO2 was produced, meaning there was no carbonate in sample
What is a positive test result
When what your testing for is present
What is a negative test result
When the thing you are testing for is not present
What ions do we add to test for sulfates
Barium ions
What is the symbol equation for testing for sulfates
Ba^2+ (aq) + SO4^2- (aq) -> BaSO4 (s)
What is the word equation for testing for sulfates
Barium ions + sulfate ions -> barium sulfate
What colour precipitate is barium sulfate
White
What is the positive result when testing for sulfate
If we see a white precipitate forming then there is a sulfate
What is the negative result of testing for sulfate
If no white precipitate forms then there is no sulfate present
What is the first step to test for sulfates
Add some dilute hydrochloric acid (HCl) into a test tube with barium ions to remove any carbonates and sulfate ions that could give us a false result as they also become a white precipitate when reacted with barium chloride solution
What is the second step to testing for sulfates
(After HCl has been added)
Add barium chloride solution (BaCl2) which contains barium ions that will cause a white precipitate to form showing a positive result
Describe the test for testing for sulfates
1) Add some dilute hydrochloric acid (HCl) into a test tube with barium ions to remove any carbonates and sulfate ions that could give us a false result as they also become a white precipitate when reacted with barium chloride solution
2) Add barium chloride solution (BaCl2) which contains barium ions that will cause a white precipitate to form showing a positive result
What are the 3 main halide ions we test for
- chloride
- bromine
- iodide
What is the first step when testing for a halide ion
Add dilute nitric acid to get rid of all carbonate and sulfate impurities
What is the second step when testing for halide ions
Add silver nitrate (AgNO3) because the silver reacts with the halide to form a precipitate
Yellow = iodide ion
Cream = bromide ion
White = chloride ion