organics II 5.4 Flashcards

1
Q

what are alcohols

A

organic molecules

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2
Q

alcohol functional group

A

-OH

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3
Q

1 carbon alcohol

A

methanol

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4
Q

2 carbon alcohol

A

ethanol

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5
Q

3 carbon alcahol

A

propanol

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6
Q

4 carbon alcohol

A

butanol

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7
Q

methanol formula

A

CH3OH

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8
Q

ethanol formula

A

C2H5OH

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9
Q

propanol formula

A

C3H7OH

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10
Q

butanol formula

A

C4H9OH

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11
Q

2 methods of making ethanol

A

hydration of ethene
fermentation of glucose

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12
Q

conditions for hydration of ethene

A

300°C
65 atmospheres
phosphoric acid catalyst

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13
Q

advantages of hydration of ethene

A

makes pure ethanol
can run continuously

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14
Q

disadvantages of hydration of ethene

A

conditions require lots of energy
non-renewable raw material used

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15
Q

hydration of ethene chemical equation

A

C2H4 + H2O –> C2H5OH

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16
Q

conditions for fermentation of glucose

A

yeast (enzymes)
30°C
anaerobic

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17
Q

advantages of fermentation of glucose

A

renewable raw material used
conditions not energy-intensive

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18
Q

disadvantages of fermentation of glucose

A

makes impure ethanol
must be done in individual batches

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19
Q

fermentation of glucose chemical equation

A

C6H12O6 –> 2C2H5OH + 2CO2

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20
Q

how can ethanol be oxidised

A

combustion
microbial oxidation
chemical oxidation

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21
Q

combustion of ethanol equation

A

C2H5OH + 3O2 –> 2CO2 + 2H2O

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22
Q

carboxylic acid functional group

23
Q

one carbon carboxylic acid

A

methanol acid

24
Q

two carbon carboxylic acid

A

ethanoic acid

25
three carbon carboxylic acid
propanoic acid
26
four carbon carboxylic acid
butanoic acid
27
methanoic acid formula
HCOOH
28
ethanoic acid formula
CH3COOH
29
propanoic acid formula
C2H5COOH
30
butanoic acid formula
C3H7COOH
31
what is vinegar
aqueous solution of ethnic acid
32
how do carboxylic acids react with metal
forms salt + hydrogen
33
observations carboxylic acid and metal reaction
effervescence solid disappears
34
what is the name for a carboxylic acid salt
-oate
35
how do carboxylic acids react with metal carbonate
forms salt, water and carbon dioxide
36
observations in carboxylic acid and metal carbonate reaction
effervescence solid disappears
37
what is an ester
carboxylic acid and alcohol join together by losing an H2O molecule
38
what do carboxylic acids lose when forming esters
OH
39
what do alcohols lose when forming esters
H
40
what is the ester functional group
-COO-
41
carboxylic acid + alcohol -->
ester + water
42
how to name an ester
alcohol (yl), acid (oate)
43
how to make an ester
1. mix the carboxylic acid and alcohol together 2. add drops of concentrated sulphuric acid (catalyst) 3. warm in a water bath 4. tip the mixture into sodium carbonate solution, neutralises the sulphuric acid catalyst
44
ester characteristics
volatile compounds distinctive smells
45
what is a polyester
polymer made of lots of molecules joined together in a chain by ester groups
46
what types of monomers make a polymer
dicarboxylic acid diol
47
how do monomers form a polymer
join into a very long alternating chain
48
what is condensation polymerisation
each time a monomer joins the end of the chain, an H2O molecule is lost
49
dicarboxylic acid
has -COOH at both ends
50
diol
as -OH at both ends
51
what are biopolyesters
biodegradable polyesters
52
how are biopolyesters broken down
microbes such as bacteria and fungi use enzymes to break down the polymer into its monomers and use them as an energy supply
53
why are biopolyesters good
reduces reliance on landfill and incineration to dispose of polyesters