Organic Chemistry Flashcards

1
Q

how can molecules be categorised as

A

molecules can be categorised as polar or non-polar

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2
Q

what to polar molecules have

A

polar bonds, which are formed between atms with different electronegativites - the tendancy for an atom to attract electrons

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3
Q

what creates a polar bond

A

because of electronegativity difference, electrons within bond tend to linger around the more electronegative atom

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4
Q

requirements for molecule to be polar

A

polar bonds ust be distributed asymmetrically within the molecule, creating a net dipole (note that just because a molecule contains polar bonds does not not mean that it is polar

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5
Q

what is a dipole

A

a seperation of negative and positive charge across the molecule

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6
Q

how to polar and non-polar molecules interact

A

they interact in different ways via the intermolecular forces that exist between molecule

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7
Q

what are dispersion forces

A

transient (short-lastinfg) forces of attraction between the temporary dipole in one molecule and the induced dipole in another.

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8
Q

what are organic compounds

A

compounds that contain carbon

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9
Q

how many bonds does carbon like to form

A

4

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10
Q

how many bonds does to following elements like to form

hydrogen
lithium
sodium
berilyium
boron
carbon
nitrogen
oxygen
fluroine
chlorine
bromine
iodine

A

1
1
1
2
3
4
3
2
1
1
1
1

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11
Q

what does each bond represent

A

2 electrons (doulbe check just incase it only applies to water)

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12
Q

when does a h bond (hydrogen bond) occur?

A

when hydrogen is attatched to nitrogen, fluorine, oxygen

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13
Q

what is a negatively charged ion

A

anion

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14
Q

what is a positively charged ion

A

cation

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15
Q

what are alkanes

A

saturated hydrocarbons organic compounds, meanign that the carbon atoms are filed with the hydrogen atoms, can be straight-chained,

can exibit structural isomerism

single-bonded carbon atoms which are attached to hydrogen atoms

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16
Q

what is the formula for an alkane

A

C_nH_2n+2

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17
Q

alkanes in order

A

methane
ethane
propane
butane
pentane
hexane
heptane
octane
nonane
decane

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18
Q

what is methane

A

CH_4

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19
Q

what is ethane

A

C_2H_6

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20
Q

what is propane

A

C_3H_8

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21
Q

what is butane

A

C_4H_10

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22
Q

what is pentane

A

C_H5_12

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23
Q

what is hexane

24
Q

what is heptane

25
what is octane
C_8H_18
26
what is nonane
C_9H_20
27
what is decane
C_10H_22
28
what are alkenes
contain at least one carbon-carbon double bond whereas alkanes do not contain double bonds referred to as unsaturated because their bonding capacity isnt fully exploited. i.e. the double-bond allows fewer hydrogen atoms to bond to the carbons. they can exhibit two forms of isomerism
29
what is the alkene form of ethane called
ethene
30
what is alkyne
hydrocarbon with a triple bond
31
what is a two carbon alkyne
ethyne (also called acetylene)
32
difference between alkanes and alkynes/alkenes
alkanes are saturates compounds, whereas alkynes and alkenes are unsaturated compounds.
33
which one is longer a carbon carbon single bond or a carbon carbon double bond
carbon carbon single bond is longer than carbon carbon double bond which is longer than the carbon carbon triple bond.
34
which bond is strongest, single double or triple
triple is storngest, single is weakest
35
what bonds does a single bond contain
1 sigma bond
36
what bonds does a double bond contain
1 sigma bond 1 pi bond
37
what bonds does a triple bond contain
1 sigma bond 2 pi bond
38
which is stronger, pi or sigma
sigma bonds are stronger than pi bonds
39
Bond order for single bond double bond triple bond
single = BO 1 double = BO 2 triple = BO 3
40
hybridisation of a carbon atom with 4 hydrogen atoms around it
S*1P*3
41
hybridisation of a bond
write the hybridisations of the atoms that the bond connects (e.g. atom 1 - atom 2)
42
formal charge formula
FE = VE - ( B + d ) FE = Formal Charge VE = Valence Electrons B = bonds attached to element d = dots attached to element
43
what is a cation carbon called
carbocation
44
what is a anion carbon called
carbanion
45
when you have an odd number of electrons
you have what is called a radical
46
what is a 1 carbon radical known as
a methyl radical
47
radicals
tend to be neutral
48
what is a lone pair
represents a pair of non bonding electrons because they're only attached to one atom
49
in a bond
you have 2 bonding electrons
50
what is an OH group
the functional group of an alcohol and alkanes follow the suffix -ol
51
what is an CHO group
aldehyde, contains a carbonyl group, a carbon double bonded to an oxygen. ends in the suffix -al
52
what is an ether
an oxygen atom in between two carbon atoms
53
what is a ketone
when the carbonyl group in the middle of the chain (e.g. propanone) suffix -one
54
what is an ester
has two oxygen atoms and a carbonyl group
55
what is a carboxylic acid
a functional group consisting of combined carbonyl group and a hydroxyl group e.g. five carbon carboyxylic acid is called pentanoic acid
56
ester nomenclature???
57