Electron configuration Flashcards

1
Q

explain electrons charge

A

Electrons have a
- ve charge
Overall Electrically Neutral

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1
Q

what makes up an atom

A

sub atomic particles

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2
Q

what is the area an electrons inhabits called

A

Electrons do not just move freely in the extranuclear space but are confined
to a particular region
Each of these regions are named Shells or Principal Energy Levels

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3
Q

formula for amount of electrons in each shell

A

Each shell fills to 2n*2 where
n is the number of the shell

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4
Q
A

Electrons have more energy the further away from the nucleus

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5
Q

why is electronic structure important?

A

Electronic structure is important because in principal
it can predict the reactivity of atoms and molecules!

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6
Q

subdivision of electronic shells

A

Shells are divided up into subshells labelled s, p, d and f

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7
Q

how are subshells numbered

A

Each of the subshells can be numbered and with this numbering they are classified into a specific orbital

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8
Q
A

Orbital: Region of space that can hold 2 electrons

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9
Q

How do we label Orbitals?

A
  1. Large number is the Shell or Principal Energy Levels
  2. The small letter refers to the shape
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10
Q

what does the letter s mean?

A

The letter
s means a spherical orbital.

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11
Q

what does the letter p mean?

A

The letter
p means a two–lobed orbital
-x, y, or z subscript on a p orbital label indicate
s
the coordinate axes the two lobes

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12
Q

what does the letter d & f mean?

A

The d and f orbitals has 5 and 7 differently shaped orbitals respectively

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13
Q

define a filled orbital

A

In general a filled orbital is where you will find an electron pair 90-95%
of the time

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14
Q

Why does an H atom have so many orbitals and only 1 electron?

A

Hydrogen: Why does an H atom have so many orbitals and only 1 electron?

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15
Q

what is an orbital

A

An orbital is a potential space for an electron, it can be empty
Atoms can have many potential (empty) orbitals

16
Q
A

Previously conceived Bohr model (electrostatic, planetary model of the atom) proven by atomic emission spectra unfortunately, failed in the case of other heavier atoms

17
Q

why does bohr model fail

A

Reason: does not predict electron-electron repulsion, other nucleus-electron attractions, also states the
electron is not allowed to occupy any of the spaces in between the orbits.

18
Q
A

Need one more property to determine how the electrons are arranged Spin – electron spins like a top

19
Q

define the pauli exclusion principle

A

Pauli Exclusion Principle – an atomic orbital can hold a maximum of 2 electrons and those 2 electrons must have opposite spins.

20
Q
A

Electrons fill into equivalent energy orbitals before pairing up

Each orbital holds 2 electrons and with their spins paired

21
Q
A

Electrons are “happy” when they are paired up in an orbital

Electrons counted like the previous two examples are in the ground state
conformation

22
Q
A
  1. Atoms have a series of energy levels called Principal Energy Levels, which are
    designated by whole numbers (
    n = 1, 2, 3, etc.)- Principle Quantum Number
    Summary: Electronic Structure of Atoms
  2. The energy of the level increases as the value of n increases.
  3. Each principal energy level contains one or more types of orbitals,
    called subshells
  4. The number of subshells in a
    given Principal Energy Levels
    also equals n.
  5. The
    n value is always used to label the orbitals of a given principal level and
    is followed by a letter that indicates the type (shape) of the orbital (
    1
    s, 3
    p, etc.)
  6. An orbital can be empty or it can contain one or two electrons, but never
    more than two. If two electrons occupy the same orbital, they must have
    opposite spins.
  7. The shape of an orbital does not indicate the details of electron movement.
    It indicates the probability distribution for an electron residing in that orbital
23
Q
A

The orbital or, space where two electrons are found, belong to a specific shell
For example: An atom with 7 electrons fills : 2 electrons in the first shell and
5 electrons in the second shell.
In orbitals, electrons fill two into the 1s orbital, two into 2s orbital
and one into 2px, one into 2py and one into 2pz

24
Q
A

Aufbau principle (German: build up) and order of orbital filling:
In the ground state of an atom or even ions: electrons fill atomic orbitals, also
obeying the Pauli Exclusion principle, in the lowest available energy levels
before filling the higher levels.
Order of Orbital and Subshell Filling
1. Each electron in an atom occupies the most stable available orbital
2. No two electrons can have identical quantum numbers
3. Orbital capacities are as follows: s: 2 electrons, p set: 6 electrons
d set: 10 electrons, f set: 14 electrons.

25
Q

Core electrons definition

A

– Inner electrons

26
Q

Valence electrons definition

A

Electrons in the outermost (highest) principal energy level
of an atom

27
Q
A

The elements in the same group on the periodic table have the same valence electron configuration Elements with the same valence electron arrangement show very similar chemical behaviour