Organic Chem Test Part 2 Flashcards

1
Q

Micelle

A

Soap molecules that clump together

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2
Q

Hydrophobic tail

A
  • one part of the soap molecule
  • non polar
  • doesn’t like water
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3
Q

Hydrophilic head

A
  • one part of the soap molecule
  • polar
  • likes the water
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4
Q

Polarity

A
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5
Q

Industrial process of saponification

A
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6
Q

Lab saponification process

A
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7
Q

Difference between industrial and lab procedure of Aspirin

A

Industrial- they will boil the beaker

Lab we set it to 80 degrees

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8
Q

The found active ingredient for the medicinal properties of many plants

A

Salicylic acid

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9
Q

Esterification reaction

A

The phenolic (OH) group in the salicylic acid is replaced with an ester group (from the acetic anhydride); sulfuric acid catalyst

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10
Q

Initial Iron (III) color

A

Apple juice color

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11
Q

Aspirin: Salicylic acid

A

Solution turned deep purple

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12
Q

Aspirin: Lab synthesized

A

Turned medium purple

Phenol source is probably unreacted salicylic acid reactant (source of error - washing crystals)

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13
Q

Commercial Aspirin

A

Turned lighter purple(or didn’t change at all)
Phenol source is probably the age of the aspirin - as it ages the aspirin reacts with water in the air and reforms salicylic acid

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14
Q

Petroleum separates into various _____ by _______

A

Fractions by distillation

Separation based on boiling point (physical not chemical)

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15
Q

Petroleum diagram in order(top to bottom)

A
*Cool (25 degrees C)
~refinery gases- bottled gas
~Gasoline(petrol)- fuel for cars
~naphtha- making chemicals
~kerosene- aircraft fuel
~diesel fuel- fuel for cars, lorries, busses
~Fuel Oil- fuel for ships, power stations
`heated crude oil
~residue- bitumen for roads and roofs 
*hot (350 degrees C)
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16
Q

Small molecules

A

Low boiling point
Very volatile
Flows easily
Ignites easily

17
Q

Large molecules

A

High boiling point
Not very volatile
Doesn’t flow easily
Doesn’t ignite easily

18
Q

C5-C12

A

Gasoline

19
Q

C10-C18

A

Kerosene/jet fuel

20
Q

C15-C25

A

Diesel fuel
Heating oil
Lubricating oil

21
Q

> C25

A

Asphalt

22
Q

Substituion

A

R+ halogen–>RHolgenR + HHalogen

23
Q

Triglyceride + alcohol—> fuel(methyl ester) +glycerol

A

Needs KOH

24
Q

Biodiesel technique used

A

Calorimetry

25
Q

Tools used in biodiesel

A

Separatory funnel and calorimeter

26
Q

Where was the fuel less dense

A

Top layer of the sep funnel

27
Q

Source of error in calorimetry

Heat gained/lost-where and how

A

Metal can absorb heat/flame distance from can/neven heating of water/poor insulation

28
Q

Saponification background

A

-soap is produce when a fat (or oil) is mixed and heated with sodium hydroxide; the fat is an organic molecule