nuclear magnetic resonance spectroscopy Flashcards
why are elements with an odd number ofprotons and electrons used
they have a significant nuclear spin
what is resonance
with the right combination of a strong magnetic field and radio frequency radiation the nucleus can absorb energy and rapidly flip between the two spin states
chmical shift
electrons shift the energy and radio frequency needed for nuclear magnetic resonance to takes place
what determines the chemical shift
chemical enviroment
what is the name of the reference chemical
tetramethylsilane (TMS)
how is NMR spectrometer run
tube is placed inside the spectrometer, wbere it is spun
the sample is given a pulse of radiation containing a range of radio frequencies
what are deuterated solvents used for
CDCl3 is comonly used as a solvent
D2O is used to identify alcoholsand NH