Amino Acide, Amides And Chirality Flashcards

1
Q

what type of amino acids are in the human body

A

alpha

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2
Q

what makes an amino acid alpha

A

the amine group is attached to the alpha carbon atom (2nd carbon after carboxyl group)

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3
Q

general formula of an amino acid

A

RCH(NH2)COOH

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4
Q

why doest the amine group react with acids to make salts

A

it is basic

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5
Q

when the amine group reacts with an acid what does it form

A

an ammonium salt

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6
Q

what is the carboxylic acid section of the amino acid able to react with and whbat do they form

A

alkalis to form salts
alcohols to form esters

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7
Q

how are carboxylic acids esterified

A

by heating with an alcohol in the presence of concentrated sulfuric acid

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8
Q

what is a zwitterion

A

within the structure of an amino acid the amine group accepts a proton from the carboxylic acid group to form an ion containing positive and negative charge

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9
Q

what is the isoelectric point

A

the ph at which the zwitterion is formed

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10
Q

what happens if an amino acid is added to a solution of greater PH than its isoelectric point

A

it behaves as an acid and looses a proton

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11
Q

what happens if an amino acid os added to a solution of lower PH than its isoelectric point

A

it acts as a base and gins a proton

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12
Q

what are amides

A

the product of reactions of acyl chlorides with ammonia and amines

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13
Q

what detrmines whether an amide is primary secondary or tertiary

A

thne number of carbons to the nitrogen

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14
Q

define sterioisomer

A

same structural formula but a different arangement of atoms in space

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15
Q

define chiral centre

A

a carbon atom that is attached to four different atoms or groups of atoms

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16
Q

define optical isomers

A

two non-superimposable mirror image structures