carbon-carbon bond formation Flashcards

1
Q

what nis a nitrile group

A

functional group -CN

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

how do you form nitriles

A

react haloalkanes with NaCN or KCN in ethanol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

mechanism of nitrile formation from haloalkanes

A

nucleophilic substitution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

mechanism of nitrile formation from aldehydes and ketones

A

nucleophilic addition

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

how do you form hydroxynitriles

A

react aldehyde or ketone/H+

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Alkylation

A

reaction that transfers an alkyl group from haloalkane to a bennzene ring

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what catalyst is needed for alkylation

A

AlCl3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

acylation

A

when benzene reacts with an acyl chloride and a ketone is formed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what catalyst is needed for acylation

A

AlCl3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly