Non-carbonyl Groups

Question 1

In a carbon-halogen (C–X) bond, the carbon atom bears a partial ________ charge while the halogen atom bears a partial ________ charge.

Answer 1

C: Partial +
X: Partial -

Question 2

Are C-X bonds polar or nonpolar?

Answer 2

Polar

Question 3

Do aliphatic halides exhibit intermolecular hydrogen bonding?

Answer 3

No

Question 4

Do aliphatic halides have lower or higher boiling and melting points than similar alkanes?

Answer 4

Higher

Question 5

Alkyl _________ have the lowest boiling points, alkyl _______ the highest.

Answer 5

Highest: Alkyl Iodides
Lowest: Alkyl Fluorides

Question 6

Are all alkyl halides soluble or insoluble in water?

Answer 6

Insoluble

Question 7

A mixture of alkyl halide and water results in the formation of ___ layers.

Answer 7

Two layers

Question 8

Are chlorinated and fluorinated halides denser than water?

Answer 8

No

Question 9

Are brominated and iodinated halides denser than water?

Answer 9

Yes

Question 10

In alkyl halides, density _________ with polyhalogenation.

Answer 10

Increases

Question 11

These compounds are sulfur analogs of alcohols and phenols.

Answer 11

Thiols or Mercaptans

Question 12

These compounds are sulfur analogs of ethers.

Answer 12

Dialkyl Sulfides or Thioethers

Question 13

The amino acid cysteine contains a _________ link. The crosslinked _________ bonds of cysteine are found in keratin (hair).

Answer 13

Disulfide

Question 14

The more S-S bonds, the ________ and less flexible the bonds are.

Answer 14

Stronger

Question 15

Nitriles, also known as _____ compounds, are organic compounds that contain the cyano functional group represented as −C ≡ N.

Answer 15

Cyano

Question 16

________, also known as cyano compounds, are organic compounds that contain the cyano functional group represented as −C ≡ N.

Answer 16

Nitriles

Question 17

The general formula of the family of nitriles is?

Answer 17

RCN

Question 18

Do nitriles and nitro compounds contain a polar or nonpolar functional group?

Answer 18

Polar

Question 19

The compound ______________ is processed in many quantities by the process of ammoxidation.

Answer 19

Acrylonitrile

Question 20

The compound Acrylonitrile is processed in many quantities by the process of?

Answer 20

Ammoxidation

Question 21

Some compounds of nitriles are mainly manufactured by heating up of carboxylic acids with the _______ compound in presence of some catalysts.

Answer 21

Ammonia

Question 22

Nitriles compounds are also formed by the process of heating ______ with the phosphorous pentoxide compound.

Answer 22

Amides

Question 23

Nitriles are somewhat like _________ solids and liquids having unique odors.

Answer 23

Colorless

Question 24

Are nitriles soluble or insoluble in water?

Answer 24

Soluble

Question 25

The hydrolysis of nitriles in the presence of an acid or a base produces ____________ and __________ _____ efficiently.

Answer 25

Carboxamides & Carboxylic Acids

Question 26

Nitriles are reduced to _______ and ________ amines by treating them with lithium aluminum hydride.

Answer 26

Primary & Tertiary Amines

Question 27

The Alkylation of nitrile compounds leads to the formation of _______ anions.

Answer 27

Nitrile Anions

Question 28

_____ compounds are organic compounds that contain the nitro functional group, -NO2.

Answer 28

Nitro

Question 29

If the nitro group is attached to an alkyl group, then it is called an _________ nitro compound represented by general formula RNO2.

Answer 29

Aliphatic Nitro Compound

Question 30

If the nitro group is attached to a benzene ring or an aryl group then, it is called an ________ nitro compound represented by ArNO2.

Answer 30

Aromatic Nitro Compound

Question 31

What is the smallest organic nitrile?

Answer 31

Ethanenitrile (CH3CN)

Question 32

Aliphatic nitro compounds are called?

Answer 32

Nitroalkanes

Question 33

Aromatic nitro compounds are called?

Answer 33

Nitroarenes