Next Step #1 Flashcards
What is micromolar?
1 x 10^-6 Molarity
Hypertonic
Higher concentration of solutes
Boiling point
When vapor pressure equals ambient pressure
Why does boiling point elevation occur?
More solute, less interface for the liquid to gas transition occur, decreases the vapor pressure and thus increases the temperature necessary to reach the boiling point.
Gamma rays are a type of _____ radiation
Ionizing
Radioactive decay is a ____ process
Irreversible
Does an alpha particle have a charge?
Yes, +2
What is one thing to keep in mind about cancer timing?
It may take a little while to develop.
Benign vs. malignant tumors
Benign: remain localized
Malignant: can invade other parts of the body in a process known as metastasis.
Angiogenesis
The development of blood vessels which can be used by cancer cells to feed them
Are chiral molecules superimposable on their mirror images?
No
Dextrorotater vs. levorotary
o Dextro (+): rotate plane polarized light in clockwise direction o Levorotary (-): rotate plane polarized light in counterclockwise direction
The more polar a compound, the _______ its solubility in an aqueous solution.
Increases
In a condenser, where does the water come in from?
Bottom
Imine vs. enamine
Imine: N=C
Enamine: C=C-NR2
The slope of the graph of displacement versus time represents _____
Velocity
The area under a curve of velocity and time represents ______.
Displacement
The attractive force of the positively-charged nucleus on the atom’s negatively-charged valence electrons is termed the _______
effective nuclear charge
What is the Newton’s Third law pair of weight caused by gravity of Earth?
Gravitational pull by the body on Earth. The gravity from Earth exerts a force on an object and that object also exerts a gravitational force on Earth.
What do noncompetitive inhibitors bind to?
Allosteric site either on the enzyme or ES complex.
When pH is less than the pka of a proton, will it be protonated or deprotonated?
Protonated
1 picogram = ____ grams
1 x10-12 grams
What are the properties of nitrogen gas?
Diatomic, inert, 80% of the air we breath.
• H2 with Pd reduces a ketone to an _____
Alkane
What can DIBAL do?
Reduce carboxylic acid to aldehyde and stop
What is unique about NaBH4?
It is a weak reducing agent and it cannot reduce carboxylic acids.
Steroids have a fused ____ ring structure
4 ring
T3 and T4 are derived from _____
Tyrosine
Compare the lasting effects of steroid hormones and peptide hormones?
Steroid hormones are longer-lasting, have a direct effect on gene transcription
Do lyases use water to cleave molecules?
No
What is the carbonyl IR peak? What is the alcohol OH peak?
Carbonyl: 1700-1750
Alcohol OH: 3200-3500
Only molecules that undergo a net change in the ________ during vibrational and rotational motion can absorb IR radiation.
dipole moment
Disulfide links only form between the side chains of _____ residues.
Cysteine
In the alpha helix, there are ____ residues per turn
3.6
Disulfide bonds contribute to ____ structure
Tertiary (and quarternary)
If you break disulfide bonds and the protein then splits onto two different places on the gel, what does this mean?
It means that the protein has quaternary structure
What is the standard hydrogen electrode half reaction?
2 H+ + 2e- H2
The O2 electron acceptor at the end of the ETC has the _______ reduction potential
Highest
Does a positive or negative cell potential correspond to spontaneity?
Positive (negative delta G and >1 Keq)
When does the angle of incident light equal the angle of reflection?
Always
What is “angle of incidence” in reference to?
In reference to the normal to the medium
Total internal reflection is only possible when ______
Going from higher index of refraction to lower index of refraction.
What is the orbital hybridization of XeF4?
sp3d2
What happens in sp3 hybridization in NH3?
Combining the 2s orbital with the 3 2p orbitals to make 4 sp3 hybridized orbitals which are lower in energy.
Water that interacts with nonpolar molecules forms a ______ shield which _____ entropy
Solvation shield which decreases entropy.