Molten Electrolysis Flashcards

1
Q

What is electrolysis?

A

The breaking down of a compound using electricity. The substance to be broken down is connected into a circuit with a cell or battery.

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2
Q

What are electrodes?

A

They connect the substance into the circuit.

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3
Q

What is the positive electrode called?

A

The anode.

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4
Q

What is the negative electrode called?

A

The cathodes.

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5
Q

What 2 things must the material on electrode be?

A

-Able to conduct electricity
-Inert (unreactive)

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6
Q

What 2 materials can an electrode be made from and are they cheap or expensive?

A

-Graphite (cheap)
-Platinum (expensive)

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7
Q

What is the electrolyte?

A

The substance to be broken down.

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8
Q

What are the only compounds that conduct electricity in electrolysis?

A

Ionic compounds conduct electricity when they are molten or dissolved as the ions are free to move.

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9
Q

Why won’t solid ionic compounds work in electrolysis?

A

Because the ions can’t move.

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10
Q

Why won’t covalent compounds work in electrolysis?

A

Because the molecules aren’t even charged.

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11
Q

what is attracted to the cathode?

A

Cations - positive anions

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12
Q

what is attracted to the anode?

A

Anions - negative ions

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13
Q

What happens at the anode?

A

Non-metal ions lose electrons to form molecules.

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14
Q

Write the half equations for the electrolysis of molten magnesium chloride (MgCl2)

A

At the anode:

2Cl- -> Cl2 + 2e-

At the cathode:

Mg2+ + 2e- -> Mg

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15
Q

What happens at the cathode?

A

Metal ions gain electrons to form atoms.

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16
Q

What are 2 observations of the electrolysis of molten magnesium chloride?

A

Some bubbles of pale green gas will be observed, some grey solid would form on the surface of the cathode.

17
Q

Are anions oxidised or reduced at the anode?

A

They are oxidised because they lose electrons.

18
Q

Are cations oxidised or reduced at the cathode?

A

They are reduced because they gain electrons.

19
Q

Write the half equations for the electrolysis of molten Al2O3:

A

At the anode:

2O 2- -> O2 + 4e-

At the cathode:

Al 3+ + 3e- -> Al

20
Q

What are 2 observations of the electrolysis of molten Al2O3?

A

Bubbles of colourless gas at the anode, a shiny grey solid at the cathode.