Energetics Flashcards

1
Q

Define activation energy:

A

The minimum amount of energy the reactant particles need in order to collide with each other and react.

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2
Q

What is an exothermic reaction?

A

A reaction that transfers energy to surroundings, usually in the form of heat.

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3
Q

What is an endothermic reaction?

A

A reaction that takes energy in from its surroundings.

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4
Q

What is an enthalpy change?

A

The enthalpy change of a reaction is the heat energy it releases or absorbs per mole.

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5
Q

What is the unit for enthalpy change?

A

kJ/mol

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6
Q

What does it mean if the enthalpy change has a + sign?

A

It absorbed heat energy - an endothermic reaction

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7
Q

What does it mean if the enthalpy change has a - sign?

A

It released heat energy - an endothermic reaction

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8
Q

What happens to the heat energy when bonds break?

A

They absorb heat energy - endothermic reaction

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9
Q

What happens to the heat energy when bonds are made?

A

They release heat energy - exothermic reaction

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10
Q

How to calculate ΔH?

A

ΔH = bonds broken - bonds made

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11
Q

What 2 equations do you need when working out and converting into ΔH in a practical?

A

Q = m x c x Δt

ΔH = -Q / moles

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12
Q

What is the c in the equations and what is its value?

A

It’s the specific heat capacity of water.

It is always 4.18 J/g/C

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13
Q

What are the 2 common errors in combustion calorimetry?

A
  1. Heat loss - most dissipates into air instead on water
  2. Incomplete combustion - releases less energy than expected
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14
Q

What substances do you need for combustion calorimetry and how much?

A

-50g water
-Methanol burner

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15
Q

What substances do you need for solution calorimetry and how much?

A

-25cm3 CuSO4(aq)
-1g Mg(s)

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16
Q

What is different error that can happen in solution calorimetry?

A

The water being heated is not longer pure so the specific heat capacity is no longer exactly 4.18.