Matter and Radiation Flashcards
What is the mass of an electron?
1/2000 atomic mass unit (amu)
What is the charge of an electron?
a negative charge of 1 electronic charge (e)
What defines the size of an atom?
The diameter of the outermost shell defines the size of the atom, which is much larger (thousands of times larger) than the size of the nucleus.
What defines the chemical properties of an atom?
The electrons and their configuration in shells, determine the chemical properties of the atom.
What are nucleons?
Protons and neutrons can be known collectively as nucleons.
What is the mass and charge of a proton?
Protons have a mass of approximately 1 amu, and a positive charge of 1 electronic charge.
What is the mass and charge of a neutron?
Neutrons have a mass of approximately 1 amu, and a zero electric charge.
What keeps the nucleus stable?
A short-range force between nucleons keeps the nucleus stable. It acts between one proton and another, between one neutron and another, and between a proton and a neutron. This force that keeps the nucleus together is known as the strong nuclear force or the strong interaction
How does the force between nucleons vary with distance?
a strong force of attraction (negative force) exists for nucleon separation below about 10-15 m and that this changes to a force of repulsion (positive force) at about 10-16 m. Therefore the nucleons are kept apart at a distance of about 5 x 10-16 m.
other than the strong interaction, what other force acts within the nucleus?
the electrostatic force of repulsion (Coulomb force) between the positively charged protons. At separations of 10-15 m to 10-16 m, the attractive strong interaction is much greater than the repulsive electrostatic force.
How many electrons are in each shell?
The maximum number of electrons that a shell can hold is 2n^2 where n is the quantum number of the shell.
The K-shell holds a maximum of 2 electrons
The L-shell holds a maximum of 8 electrons
The M-shell holds a maximum of 18 electrons
How does the energy differ between bound electrons in different shells?
Electrons in different shells have different energies and, since the electrons are held or bound within the atom, these energies are negative. The outermost shells have the greatest (i.e. least negative) energy.
What force binds electrons in their shells?
electrostatic force between it and the positively charged nucleus. This attractive force gives the electron negative potential energy.
What is the binding energy of an electron?
Electrons attached to atoms need to be given energy to become free, that is to cancel out their negative energy and achieve zero energy. The energy needed to free an electron from an atom is called the binding energy of the electron. Binding energy is a positive quantity; its magnitude is equal to that of the actual (negative) energy of a bound electron
Are the binding energies higher or lower with greater atomic number?
The binding energies increase with atomic number i.e. the number of protons on the nucleus. At higher atomic numbers, the electrons feel a greater force from the greater number of protons, which represent a greater positive charge.
Where is the positive binding energy greatest?
The positive binding energy is greater for inner shells than for outer shells, while the reverse is true for the actual (negative) energy. The inner shells are closer to the nucleus and so that the electrons feel a greater attractive force.
What are the units for electron binding energies?
Both actual electron energies and binding energies are expressed in electron volts (eV) or, more usually, kilo electron volts (keV), where 1 eV = 1.6022 x 10-19 joule (J).
What is electron excitation?
At a certain distance from the nucleus there is a shell with zero energy - this is the boundary of the atom. A large number of unoccupied closely spaced shells exist between the outermost one occupied by electrons and this boundary. Electrons may be raised to these unoccupied shells by a process known as excitation.
What is ionisation?
An electron not attached to an atom is called a free electron. The process of releasing a bound electron from an atom is called ionisation; the neutral atom is left as a positive ion.
What is the equation for kinetic energy?
Kinetic energy = (mass x velocity^2)/2
What is a nuclide?
Atoms whose nuclei have the same atomic number and the same mass number constitute a particular nuclear species or nuclide.
What determines atomic number?
The atomic number is the number of protons in the nucleus.
What determines mass number?
The mass number is the total number of protons and neutrons in the nucleus
True or false - Electron energy levels are equally spaced
False. The separation of the energy levels decreases (i.e. they get closer together) as the distance from the nucleus increases.
True or false - The electron energy levels of tungsten are the same as those of copper
False. The atomic number of tungsten (74) is greater than that of copper (29) and so for each electron shell, the binding energy for tungsten is greater than that for the same shell of copper.
True or false - Electrons in the K-shell have less kinetic energy than L-shell electrons
False. The closer an electron shell is to the nucleus, the greater is the electron velocity and hence kinetic energy.
True or false - Electrons in the K-shell have a greater negative value of potential energy than L-shell electrons
True. The closer an electron shell is to the nucleus, the greater is the attractive force of the nucleus on the electrons and hence the greater is the magnitude of the negative potential energy. This is always larger than the magnitude of the positive kinetic energy of the electrons and so the total energy is negative.
True or false - The electron has zero mass
False. The electron’s mass is 0.00055 amu or 9.109 x 10-31 kg.
What atomic property is associated with radioactive decay?
nuclear instability - Radioactive decay is caused by nuclear instability due to a combination of protons and neutrons that does not produce a balance between repulsive and attractive forces. It is usually the case that particles are emitted from (or an electron captured by) the radioactive parent nucleus during its transformation or decay to a daughter nucleus (which might itself be stable or radioactive).
What are unstable nuclides called?
radionuclides
What is radioactivity?
the process whereby radionuclides are transformed into other nuclides, which may be stable or unstable.
How is the activity of a radionuclide measured?
number of nuclear transformations per second.
What is an isotone?
Different nuclides with the same value of N are called isotones; for example, the nuclides boron-12 and carbon-13 both contain 7 neutrons and so they are isotones
What does the term metastable mean?
Normally the nucleus of an atom is in its ground (lowest energy) state. However some radionuclides can exist for a significant period of time with the nucleus in an excited (higher energy) state before falling to the ground state. Such radionuclides are called metastable. The best known example in medicine is 99mTc (used in many gamma camera imaging procedures). The ‘m’ stands for metastable
What is an isotope?
isotopes are nuclides of the same chemical element (i.e. they have the same atomic number Z) with different neutron number N and mass number A, for example, 123I, 127I and 131I are isotopes of iodine
how does the balance between protons and neutrons change as Z increases in stable nuclides?
Low atomic number nuclides have similar numbers of neutrons and protons. As Z increases a greater number of neutrons is required for nuclear stability.
The plot of stable nuclides thus approximates to a straight line for lighter elements near the origin, but becomes progressively more curved for heavier elements
If a nucleus has Too many protons and neutrons how will it decay?
Alpha (α) decay
If a nucleus has too many neutrons how will it decay?
Beta minus (ß-) decay
If a nucleus has too few neutrons how will it decay?
Electron capture (EC) and positron emission (β+) decay
What is the decay constant?
λ is known as the decay constant. It is characteristic of the parent radionuclide and a measure of its instability.
λ is related to the half-life (t½) by the formula: λ = ln2/t1/2 = 0.693/t1/2
how can you define half-life?
The half-life of the parent, t½ is the time taken for half of its atoms to decay. Alternatively, half-life may be defined as the time taken for the activity to reduce to half of its initial value.
How is radioactivity changed over time?
activity of a radioactive sample decays exponentially with time in exactly the same way as the number of radioactive atoms in that sample i.e. with the same decay constant and half-life. After one half-life (t½) the activity is reduced to one half of its original value
What units are used to measure radioactivity?
The S.I. unit of activity is the becquerel (Bq).
1 Bq = 1 transformation/second
in practice radioactivity is usually measured in units of kilobecquerel (kBq), megabecquerel (MBq) or gigabecquerel (GBq):
1 kBq = 103 Bq
1 MBq = 106 Bq
1 GBq = 109 Bq
What makes up alpha radioactivity?
Alpha particles consist of two protons and two neutrons is emitted from the nucleus. The daughter nucleus is thus a different element from the parent, with atomic number reduced by two and mass number reduced by four They are thus helium ions, and are positively charged. They are relatively heavy particles, with a short range
What makes up Beta radioactivity?
In beta decay a neutron is converted into a proton and an electron. The electron is emitted from the nucleus, in the form of a beta particle.
They are much smaller and lighter than alpha particles. They carry negative charge. It is convenient to sub-divide beta particles into negative electrons (β-) and their anti-matter equivalents, positrons (β+), which carry a positive charge. β- particles are sometimes known as negatrons.
The daughter nuclide thus has the same mass number as the parent, with atomic number increased by one.
What makes up gamma radioactivity?
Gamma rays are photons, at the high energy end of the electromagnetic spectrum. They are identical to x-rays of the same energy apart from their origin. (Gamma rays are emitted from nuclei of radioactive atoms; x-rays are a result of electron energy changes.)
Following radioactive decay, the nucleus of the daughter nuclide may be left in an excited state. Gamma rays carry away the energy that is present in the excited daughter nucleus as it de-excites in one or more stages to the ground state. Gamma radiation is the result of transitions between nuclear energy levels and gamma photon energies correspond to differences between these levels
What makes up positron emission radioactivity?
Neutron-deficient radionuclides may also decay by positron emission. In this process a proton is converted into a neutron and a positron, which is emitted from the nucleus: The atomic number thus reduces by one and the mass number stays the same
p → n + β+
What is Auger electron radioactivity?
Auger electrons are electrons which are ejected from electron shells as a result of some radioactive decay processes which create electron shell vacancies. The emission of Auger electrons is a process which competes with the emission of characteristic x-rays.
What is electron capture radioactivity?
Radionuclides with too few neutrons for stability decay via either electron capture (EC) or positron emission. In the process of electron capture an inner shell electron, normally a K-shell electron, is captured by the nucleus. This causes a proton to be converted into a neutron:
p + e- → n
The mass number thus stays the same and the atomic number decreases by one.
What is isomeric transition?
A radionuclide in metastable excited state decays to the ground state by isomeric transition (IT).
emits one or more gamma photons as it falls to the ground state, either directly or in stages (via intermediate excited states). However, if the excited state is metastable, the daughter nucleus exists in this state for a longer period before decaying to the ground state.
During isomeric decay, the energy difference between excited and ground nuclear states is emitted as gamma radiation.
Mass number and atomic number are unchanged by an isomeric transition (and by internal conversion).
What is the energy from within a positron -electron pair?
the mass of a positron has an energy equivalence of 511 keV. However it is not possible to conjure up a positron on its own without producing a corresponding electron. A positron-electron pair has energy equivalence of 1.02 MeV and this is the threshold energy difference between parent and daughter ground state nuclear energy levels for radionuclides to be able to decay by positron emission.
A positron exists for only a very short time before interacting with an electron. The matter-antimatter particles cannot coexist and both disappear, with their mass being converted to energy in the form of two 511 keV gamma rays travelling in opposite directions. This 511 keV gamma radiation, sometimes known as annihilation radiation, is the basis of image formation in positron emission tomography (PET).
What is internal conversion?
Internal conversion (IC) competes with isomeric decay. In IC, the energy difference is used to release a bound electron from an electron shell; any energy in excess of the electron binding energy appears as kinetic energy of the internal conversion electron.
what is ionising radiation?
radiation that has sufficient energy to overcome the binding energy of the most tightly bound electrons in atoms
what can charged particles be deflected by?
magnetic and electrical fields
What is 1 quanta of charge?
The quantum of charge is 1.9 x 10-19coulomb (C).
what is the difference bewteen x-rays and gamma rays?
X-rays are only distinguishable from gamma rays by their source. They are produced in an x-ray tube, which means that x-ray production may be stopped rapidly by switching off the supply of electrical energy to the tube. Gamma rays are produced by decay processes within unstable radionuclides. It is not possible to switch on or off the production of gamma radiation.
what is the photon energy range for diagnostic radiography?
The photon energies used for diagnostic radiography are in the range 10-150 kilo electron volts (keV).
What is the equation for photon energy?
Ep=hf(wherehis Planck’s constant).
what is the equation for xray wavelength?
c = fλ therefore λ = c/f (c=speed of light)
What is the typical range of electromagnetic radiation wavelength (λ) for x-rays used in diagnostic radiology?
an x-ray photon energy range of 10-150 keV corresponds to a wavelength range of about 10-120 picometres
How do you calculate the kinetic energy of an object?
The KE in joules (J) of a moving object is given by half the product of its massm(kg) and the square of its velocityV(ms-1)
Why is kinetic energy important in the production of xrays?
In an x-ray tube it is the KE of electrons (accelerated across the x-ray tube by the large potential difference) that is converted into x-rays and heat by the law of conservation of energy.
How can attenuation be thought about with an equation?
Attenuation = absorption + scatter
What leads to total xray photon attenuation?
the photoelectric effect. The x-ray photon transfers all its energy to a bound electron. Some of it is used to overcome the binding energy and the remainder appears as KE of the electron, which is now free (of the atom) and called a photoelectron.
What leads to xray photon scattering?
Photon scattering with partial absorption is called Compton scattering. The absorbed energy appears as KE of an electron, which is called the Compton recoil electron.
what happens to photoelectrons and compton recoil electrons in tissue?
Of course, both photoelectrons and Compton recoil electrons are charged particles, and they lose their KE in multiple interactions with the surrounding tissue
How can the penetrating power of an xray beam be described?
by its Half-value thickness