Macromolecules #1: Carbohydrates (Saccharides) Deck #1 Flashcards
What are saccharides composed of?
Composed of monomers with the empirical formula CH2O.
What are monomers distinguished by?
The number of #Cs (carbons) and the type of carbonyl group.
How do monomers exist?
In a linear or ring-like state.
What may saccharides be?
Isomers like fructose and glucose, which have the same chemical formula but different structures.
What is another name for monosaccharides?
Simple sugars
What do all monosaccharides have?
The formula, C6H12O6
What is an example of a monosaccharide (that has a ring structure)?
Glucose
What makes a carbonyl a carbonyl?
The location of the bond.
Aldose (Aldehyde) Triose (3C) Common Saccharide
D-Glyceraldehyde
Aldose (Aldehyde) Pentose (5C) Common Saccharide
D-Ribose
Aldose (Aldehyde) Hexose (6C) Common Saccharide #1
D-Glucose
Aldose (Aldehyde) Hexose (6C) Common Saccharide #2
D-Galactose
Ketose (Ketone) Triose (3C) Common Saccharide
Dihydroxyacetone
Ketose (Ketone) Triose (3C) Common Saccharide
D-Ribulose
Ketose (Ketone) Hexose (6C) Common Saccharide
D-Fructose
What is D-Glyceraldehyde important for?
Important for link between photosynthesis and cellular respiration processes.
Where is D-Ribose found?
In RNA
What is D-Glucose?
An isomer
What does D-Glucose have that is different than regular Glucose?
Orientation of bonds (different isotope of glucose)
How do we interact with D-Glucose? As what?
Eat mostly; as regular sugar
What is D-Galactose?
Milk sugar
What are both D-Glucose and D-Galactose classified as?
Safe sugars
What organ is Ketone broken down with?
Kidney
What is D-Fructose?
Safest nutritional content
What is Ribulose part of?
Plant sugars
What is Dihydroxyacetone part of?
All metabolic processes
What type of bonds (in terms of energy) are all carbon-hydrogen bonds?
High energy bonds with high numerical value
Breaking down monosaccharides results in what?
Very little waste product.
What happens to monosaccharides in water?
A reversible reaction to form a ring.
One of the OH groups does what to the carbonyl group?
“Attacks” the carbonyl group to form a ring.
What does the ring structure have?
Isomers (Same molecular structure, different atomic arrangement)
Alpha and Beta Glucose OH points in what direction?
Downward (Z-Plane)
Why don’t Alpha and Beta Glucose form linear structures?
Because it is easy to break.
What is another name for disaccharides?
Double sugars
What is the formula for all disaccharides?
C12H22O11
What is an example of a disaccharide?
Sucrose (table sugar)
What do disaccharides consist of?
Two monosaccharides linked together
What do disaccharides hit the digestive system as?
Monosaccharides
When monosaccharides come together, what happens?
The water molecule is removed
When monosaccharides split apart, what happens?
The water molecule comes back
What monosaccharides is sucrose made up of?
Fructose and Glucose
What does fructose look like?
Looks like a house (pentagon-shaped)
What does glucose look like?
Is hexagon-shaped
What are simple carbohydrates?
Monosaccharides
Disaccharides
What are examples of monosaccharides?
Fructose (fruit and honey)
Glucose (Photosynthetic product)
What are examples of disaccharides?
Sucrose (table sugar)
Lactose (milk)
What are two types of complex carbohydrates?
Polysaccharides
Oligosaccharides
What are polysaccharides formed by?
Dehydration synthesis of monosaccharides
What is an oligosaccharide?
A short saccharide chain
What is a glycosidic bond?
Bond between saccharide subunits (1,4 or 1,6 glycosidic linkage)
What foods are polysaccharides found in?
Pasta, Rice, Bread, Corn, Vegetables
Dehydration =
Removal of water molecule
Join Two monosaccharides =
Removal of water molecules (1 oxy 2 hydro)
Adding water back in =
Hydrolysis
What are examples of complex carbohydrates?
Amylose (straight chain plant starch)
*Amylopectin (branching plant starch)
*Cellulose (plant cell walls)
*Glycogen (animal cells)
*Chitin (insect exoskeleton)
What contains Amylose?
Fake meat (plant-based) products contains it
What contains Amylopectin?
Plant-based liquid products
What contains Cellulose?
Indigestible starch in plant cell walls (humans can’t digest it)
What contains Glycogen?
Found in liver (storage component for carbs)
What contains Chitin?
Insect shells have it
Usually glucose molecules are bonded between what?
C1 and C4 (straight chains)
Bonding between what is possible?
C1 and C6 is possible (branching)
What is the main function of Carbohydrates? What type of Carbohydrate performs this function?
Primary Energy Source:
Simple sugars (Mono and Disaccharides)
Primary function is what?
Immediate energy source for the cell
Monosaccharides (i.e. glucose) is produced by what process?
Photosynthesis
What is monosaccharides (i.e. glucose) converted into ATP by?
Cellular Respiration
What does body go to when it needs energy?
Carbohydrates
What is the cleanest to break down into energy?
Carbohydrates
What is another main function of Carbohydrates? What type of Carbohydrates performs this function?
Temporary Energy Storage Molecules; Polysaccharides
What is one example of these temporary energy storage molecules?
Starch in plants
What is starch in plants?
Products of photosynthesis (glucose) are stored as starch in amyloplasts of plant cells.
What is another example of these temporary energy storage molecules?
Glycogen in animals
What is glycogen in animals?
when animals ingest excess carbohydrates, it is stored in the liver as the polysaccharide glycogen.
Humans don’t get enough what in lifetime?
Carbohydrates
What happens if carbohydrates are stored in the liver too long?
Carbohydrates are transferred as fat.
Do we get energy from cellulose?
No, because we don’t have the enzymes to digest it.
What is the difference between starch and cellulose?
Starch: Bonds all facing up
Cellulose: Bonds alternating up and down
What is a third function of carbohydrates?
Structural Molecules
What do carbohydrates being structural molecules mean?
Provide structure or rigidity
What are examples of carbohydrates being structural molecules?
Cellulose as plant cell wall
Chitin as insect and arthropod exoskeletons
Cells walls of fungi
Is energy stored in bonds of structural molecules?
No energy is stored
What is a fourth function of carbohydrates?
Carbohydrates in Membranes
What do carbohydrates in membranes act as?
Cell surface markers, cell-to-cell signaling, cell anchoring
Carbohydrates can be attached to what?
Other molecules embedded in cell membranes
Glyco-” is term for what? Provide example too.
Other molecules embedded in cell membranes (e.g. glycoprotein = carbohydrate attached to protein)
What is the most common organic compound on earth? What does it make?
Cellulose
-33% of all plant matter
-90% of cotton
-50% of wood
What are the processes by which complex carbohydrates are formed and broken down?
-Dehydration Synthesis (formed)
-Hydrolysis (Broken down)
What does dehydration synthesis involve?
Combining simple molecules to form a more complex one with the removal of water
Example of dehydration synthesis reaction
monosaccharide + monosaccharide —-> disaccharide + water
C6H12O6 + C6H12O6 —-> C12H22O11 + H2O
Polysaccharides are formed from what?
Repeated dehydration syntheses of water
Polysaccharides are what?
The stored extra sugars known as starch
Polysaccharides breaking down involves what?
Fermentation (forms gas)
What does hydrolysis involve?
Addition of WATER to a compound to SPLIT it into smaller subunits
What is hydrolysis also called?
Chemical digestion
Example of a hydrolysis reaction
disaccharide + H2O —> monosaccharide + monosaccharide
C12 H22 O11 + H2O —> C6H12O6 + C6 H12 O6