M6 Topic 3 Quantitative Analysis Flashcards

1
Q

what is the acid/ base ionisation constant equation

A

Kₐ/Kb = reactants(ions)/products

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2
Q

what is the acid/ base ionisation constant equation used for

A

to determine the strength of an acid/base

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3
Q

How does the value of the acid/base ionisation constant (Kₐ/Kb) dictate the strength of an acid/base

A
  • higher Kₐ/Kb stronger acid/base

- lower Kₐ/Kb lower acid/base

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4
Q

what happens when you multiply acid and base ionisation constant (Kₐ x Kb)

A

you get the water ionisation constant (Kw)

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5
Q

what are organic bases

A

bases that contain carbon atoms

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6
Q

what are indicators

A

substances that change colour with pH, generally weak acids or bases

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7
Q

what type of salt does a strong acid + strong base give

A

neutral salt

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8
Q

what type of salt does a strong acid + weak base give

A

acidic salt

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9
Q

what type of salt does a weak acid and strong base give

A

basic salt

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10
Q

what is a buffer

A

a solution that is added to another solution in order to maintain a constant pH when a small amount of acid or base is added

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11
Q

what is a buffer made out of

A

a mixture of either weak acid or base with its conjugate pair

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12
Q

what is the equivalence point

A

the point at which all the solution has been neutralised

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13
Q

how can a buffer be located on a equilibrium graph

A

in the middle of where the trend line plateaus

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14
Q

what is buffer capacity

A

the amount of acid or base that can be added to a given volume of a buffer solution before the pH changes significantly

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15
Q

what dictates the buffer capacity

A

the amount of weak acid/base and conjugate pair in the buffer mixture

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16
Q

what is the Henderson-Hasselbalch equation

A

pH = pKa + log dissociated acid [A-] / [undissociated acid [HA]

17
Q

what is the Henderson-Hasselbalch equation used for

A

calculating the pH of buffer solutions (must assume x is small)