Lipids Flashcards
what does lipid contain?
- C, H, O
- soluble in non-polar organic solvents
- Includes: mostly triglycerides
- fats: solid at room temp.
- oils: liquid at room temp.
- 3 fatty acids + glycerol
- other lipids:
- phospholipids
- free fatty acids
- cholesterol
fatty acids
- contain an even # of carbon atoms
- unbranched lines
- have carboxyl group on one end (-COOH) & methyl group (CH3) on the other end
fatty acid chain lengths
short: 2-6C
medium: 8-12C
long: 14-24C
- as the chain increases = the melting point increases
- fatty acids synthesized by plants & animals =
- mostly long chain
- 16-18C fatty acids
saturate fats
- NO DOUBLE BONDS
- solid at room temperature:
- Butter, shortening, lard, coconut oil, palm oil, and
fully hydrogenated vegetable oils - Poultry skin, whole milk
- Butter, shortening, lard, coconut oil, palm oil, and
mono-unsaturated fats
- ONLY one double bond
- liquid at room temperature:
- Olive oil, canola oil, peanut oil
- Other sources: avocado, almonds,
cashews, pecans and sesame seeds
(tahini paste)
poly-unsaturated fats
- 2 or MORE double bonds
- include:
- omega 3 FAs: linolenic acid
- omega 6 FAs: linoleic acid
- rich sources: vegetable oils
cis vs trans chain
cis: has a bent in the chain
trans: NO bent in the chain -> straight
trans-fatty acids
- natural or manufactured
- 1+ double bond
- unsaturated FA that acts like saturated FA
what acid can be synthesized by linoleic acid?
Arachidonic acid = not essential
EXCEPT cats
what omega position can animals synthesize FAs?
- Omega 9
NOT omega 3 & 6 = must be derived from the diet
- cold water fish accumulate HIGH omega 3 FAs
what acid(s) can be synthesized by linolenic acid?
- eicosapentaenoic acid (EPA)
- docosahexaenoic acid (DHA)
what are the physical traits for FAs?
- Form membranes, micelles, liposomes
- Orient at water: oil interface
- Contain hydrophobic and hydrophilic groups
- Lipid bilayer for membranes
- micelles formed during digestion
FAs forms “soaps” with cations:
- Na & K soaps = water soluble
- Ca & Mg soaps = NOT water soluble (poorly digested)
what type of FA does great with oxygen present?
- unsaturated FAs:
- auto-oxidation, peroxidation, rancidity
- free radicals formed
- antioxidants prevent oxidation
hydrogenation / saturation
- making unsaturated FAs -> saturated FAs
- convert by rumen microbes
- create trans-FAs
what are the functional properties of hydrogenation/saturation?
excess energy from carbohydrates, proteins, and lipids are stored as triglycerides in adipose tissue
- provide insulation to the body from cold
- mechanical insulation
- electrical insulation
- supply essential FAs (EFAs)
- formation of cell membranes
- help transport fat-soluble vitamins
- help control appetite