Lipids Flashcards

1
Q

Lipids (from the Greek ____,___)

A

lipos, fat

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2
Q

constituents of plants or animals that are characterized by their solubility properties.

A

Lipids

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3
Q

In particular, lipids are insoluble in water but are soluble in nonpolar organic solvents, such as____

A

diethyl ether.

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4
Q

Lipids can be extracted from ____and____ by organic solvents.

A

cells and tissues

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5
Q

This solubility property distinguishes lipids from three other major classes of natural products

A

carbohydrates, proteins, and nucleic acids

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6
Q

Fats and oils are triesters of glycerol and are called

A

triglycerides

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7
Q

When we boil a fat or oil with alkali and acidify the resulting solution, we obtain glycerol and a mixture of fatty acids. The reaction is called

A

saponification

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8
Q

There are two types of triglycerides

A

simple triglycerides & mixed triglycerides

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9
Q

which are highly unsaturated, are converted into solid vegetable fats by catalytically hydrogenating some or all of the double bonds

A

Vegetable oils

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10
Q

illustrated by the hydrogenation of glyceryl trioleate to glyceryl tristearate.

A

hardening

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11
Q

made by hydrogenating cottonseed, soybean, peanut, or corn oil until the desired butter-like consistency is obtained. The product may be churned with milk and artificially colored to mimic butter’s flavor and appearance.

A

margarine

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12
Q

constitute about 40% of cell membranes, the remaining 60% being proteins

A

Phospholipids

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13
Q

Phospholipids are related structurally to fats and oils, except that one of the three ester groups is replaced by a

A

phosphatidylamine

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14
Q

The fatty acid portions are usually

A

palmityl, stearyl, or oleyl

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15
Q

Phospholipids arrange themselves in bilayers in membranes, with the two hydrocarbon “____” pointing in and the polar phosphatidylamine ends constituting the membrane surface.

A

tails

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16
Q

play a key role in biology, controlling diffusion of substances into and out of cells

A

Membranes

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17
Q

differ from fats and oils in that they are simple monoesters. The acid and alcohol portions of a wax molecule both have long saturated carbon chains.

A

Waxes

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18
Q

Waxes are more ____, _____, and ____ than fats

A

brittle,harder, and less greasy

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19
Q

They are used to make _____, _______, _____, and __________, as well as candles and phonograph records

A

polishes, cosmetics, ointments, and other pharmaceutical preparations

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20
Q

True or false

In nature, waxes coat the leaves and stems of plants that grow in arid regions, thus reducing evaporation

A

True

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21
Q

True or false

Similarly, insects with a high surface-area-to-volume ratio often have a coating of a natural protective wax.

22
Q

Lipids are hydrophobic means?

A
hydro= "water"
phobic= "fear of"
23
Q

Olive oil gives ___% oleic acid

24
Q

gives 43% palmitic acid and 43% oleic acid, with lesser amounts of stearic and linoleicacids

25
gives at least 14 different fatty acids on hydrolysis and is somewhat exceptional in that about 9% of these acids have fewer than 10 carbon atoms
Butterfat
26
What is it that makes some triglycerides solids (fats) and other liquids (oils)?
- The distinction is clear from their composition. Oils contain a much higher percentage of unsaturated fatty acids than do fats.
27
T or F | The melting points of unsaturated fatty acids are appreciably "higher" than those of saturated acids
F (lower)
28
T or F The same difference applies to trigycerides: The more double bonds in the fatty acid portion of the triester, the "lower" its melting point.
T
29
When a fat or oil is heated with alkali (e.g.,NaOH), the ester is converted to glycerol and the salts of fatty acids. The reaction is illustrated here with the saponification of_____?
glyceryl tripalmitate
30
Categories of Lipids?
Triglycerides Phospholipids Steroids Waxes
31
solid at room temperature used by animals?
fats
32
liquid at room temperature used by plants?
oils
33
hydrophilic head means
"water- loving"
34
hydrophobic tail means
"water-hating"
35
Non-polar & repel water
waxes
36
are extremely important, mainly because of their unique properties in regard to water
Phospholipids
37
are similar to triglycerides in that they contain glycerol & two fatty acids
Phospholipids
38
are lipids because they are hydrophobic and insoluble in water, but they do not resemble lipids since they have a structure composed of four fused rings.
steroids
39
the most common steroid and is the precursor to vitamin D, testosterone, estrogen, progesterone, aldosterone, cortisol, and bile salts.
Cholesterol
40
steroids sources?
- Cholesterol (most common) - Testosterone (male steroid hormone) - Estrogen (who use anabolic steroids for bodybuilding) - Vitamin D(known for its important role in regulating body levels) - cortisone (type of anti-inflammatory drug) - plasma membrane ( lipophilic suggesting they intercalate into the bilayer of target cell plasma membranes,)
41
Only single carbon to carbon bonds known as_____
saturated fatty acid
42
have one to several double bonds
unsaturated fatty acid
43
Lipids are classified by their___
structure
44
lipids do not dissolve in water because they are
non-polar
45
Saturated fats have-
- single bond - straight structure - solidity at room temperature
46
A lipid is a polymer that is made of what kind of polymer?
fatty acids and a glycerol
47
A phospholipid bilayer comprises what part of cell?
cell membrane
48
The C-O-O-H on the end of a fatty acid structure is called a
carboxyl group
49
Lipids are made up of carbon, hydrogen and ____
oxygen
50
Triglyceride is made up of ______backbone
glycerol
51
A fatty acid consists of a hydrocarbon chain, methyl end and _______group
carboxyl group
52
how do lipids function for cells and organisms?
store energy