lect 30 Flashcards
what are the types of reactions in the atmosphere?
- thermodynamic calculations
- kinetic calculations
- photochemical reactions
- free radical reactions
what are thermodynamic calculations 1?
what are thermodynamic calculations 2?
what are thermodynamic calculations 3?
what are kinetic calculations 1?
what are kinetic calculations 2?
what are kinetic calculations 3?
what are the principles of photochemistry?
what are photochemical reactions?
what are free radical reactions?
what is a radical?
what are radical addition reaction?
what is the graph of atmospheric chemical and photochemical processes?
what are the classes of aerosols?
-carbonaceous particles
-metal oxides and glasses (eg SiO2, Fe2O3)
-water
-dissolved ionic species (ex. SO32-), ionic solids (ex: NaCl)
what are the processes affecting particulates?
-diffusion
-coagulation leading to sedimentation (dry deposition)
-scavenging by precipitation
-wet deposition (condensation with water and other vapours)
-reaction with atmospheric gases
the chief sink is wet scavenging or wet deposition
what are the primary sources of aerosols?
- dispersion aerosols
-particles >1um such as dust
-natural: sea spray, wind-blown, volcanic dust
-man-made: coal grinding, quarrying, agriculture “off-road” vehicles - biological materials
-outdoor air: spores, insect fragments, grains and pollen
-indoor air: vegetable dusts, hair, skin, feathers, dander, bacteria, fungi, micro-organisms - combustion
-smoke and soot from combustion of carbonaceous fuels
-fly ash (from burning fuels with large ash content)
what are examples of secondary sources of aerosols?
what are the overall primary and secondary aerosol sources?
what are organic components of aerosols?
what are examples of organic components of aerosols?
what is the example of terpenes of organic components of aerosols?
what is the graph of a carbon soot particle?
what are the methods of aerosol control for larger particulates (0.1-100um)?
what are the methods of aerosol control for smaller particulates (0.01-10um)
what is electrostatic precipitators?
wet or dry based methods
what is the IPCC?
what are the findings of the IPCC?
what is the graph of comparing risks from rising temperature?
what did a previous version state?
what is the window?
what are the reactions of atmospheric oxygen?
what are reactions of atmospheric nitrogen?
what is atmospheric water?
what is the influence of the anthrosphere?
what is the chemical fate and transport in atmosphere?