lect 30 Flashcards

1
Q

what are the types of reactions in the atmosphere?

A
  1. thermodynamic calculations
  2. kinetic calculations
  3. photochemical reactions
  4. free radical reactions
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2
Q

what are thermodynamic calculations 1?

A
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3
Q

what are thermodynamic calculations 2?

A
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4
Q

what are thermodynamic calculations 3?

A
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5
Q

what are kinetic calculations 1?

A
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6
Q

what are kinetic calculations 2?

A
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7
Q

what are kinetic calculations 3?

A
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8
Q

what are the principles of photochemistry?

A
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9
Q

what are photochemical reactions?

A
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10
Q

what are free radical reactions?

A
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11
Q

what is a radical?

A
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12
Q

what are radical addition reaction?

A
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13
Q

what is the graph of atmospheric chemical and photochemical processes?

A
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14
Q

what are the classes of aerosols?

A

-carbonaceous particles
-metal oxides and glasses (eg SiO2, Fe2O3)
-water
-dissolved ionic species (ex. SO32-), ionic solids (ex: NaCl)

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15
Q

what are the processes affecting particulates?

A

-diffusion
-coagulation leading to sedimentation (dry deposition)
-scavenging by precipitation
-wet deposition (condensation with water and other vapours)
-reaction with atmospheric gases

the chief sink is wet scavenging or wet deposition

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16
Q

what are the primary sources of aerosols?

A
  1. dispersion aerosols
    -particles >1um such as dust
    -natural: sea spray, wind-blown, volcanic dust
    -man-made: coal grinding, quarrying, agriculture “off-road” vehicles
  2. biological materials
    -outdoor air: spores, insect fragments, grains and pollen
    -indoor air: vegetable dusts, hair, skin, feathers, dander, bacteria, fungi, micro-organisms
  3. combustion
    -smoke and soot from combustion of carbonaceous fuels
    -fly ash (from burning fuels with large ash content)
17
Q

what are examples of secondary sources of aerosols?

18
Q

what are the overall primary and secondary aerosol sources?

19
Q

what are organic components of aerosols?

20
Q

what are examples of organic components of aerosols?

21
Q

what is the example of terpenes of organic components of aerosols?

22
Q

what is the graph of a carbon soot particle?

23
Q

what are the methods of aerosol control for larger particulates (0.1-100um)?

24
Q

what are the methods of aerosol control for smaller particulates (0.01-10um)

25
Q

what is electrostatic precipitators?

A

wet or dry based methods

27
Q

what is the IPCC?

28
Q

what are the findings of the IPCC?

30
Q

what is the graph of comparing risks from rising temperature?

31
Q

what did a previous version state?

32
Q

what is the window?

33
Q

what are the reactions of atmospheric oxygen?

34
Q

what are reactions of atmospheric nitrogen?

35
Q

what is atmospheric water?

36
Q

what is the influence of the anthrosphere?

37
Q

what is the chemical fate and transport in atmosphere?