lect 29 Flashcards

1
Q

the chemistry of acid rain from sulphur oxides complex because it can _____________

A

be deposited in various forms:
1. can react to form H2SO3
2. can be oxidized to SO3(g) and precipitate as H2SO4(aq)
3. can precipitate as wet deposition or assoc. within particulate matter (deposits as sulfite or sulphate ions)

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2
Q

what is the oxidation of SO2?

A
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3
Q

what is the homogenous gas phase oxidation?

A
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4
Q

what is the homogenous water phase reaction?

A
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5
Q

what are the details of mechanism of oxidation of SO2 in clouds or raindrops still uncertain:

A
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6
Q

what is the cycle of gas phase oxidation and water-phase oxidation?

A
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7
Q

what is the gibbs free energy of phases?

A
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8
Q

what is adsorption and distribution equilibria?

A
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9
Q

what is the graph of a water droplet?

A
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10
Q

what are SO2 emission sources?

A
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11
Q

what is the heterogenous oxidation of SO2 on particles?

A
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12
Q

what is the oxidation and deposition of SOx?

A
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13
Q

what are the effect of acidic emissions?

A

due to either effects of:
-1. effects of gaseous pollutants
-2. effects of lowered pH on water soil, or other materials

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14
Q

what are the effects on natural waters of acidic emissions?

A
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15
Q

what is the normal pH in northern america?

A
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16
Q

what is the wet deposition of sulfate?

17
Q

what is the wet deposition of nitrite?

18
Q

what happened in lakes in Adirondack region?

19
Q

what are the effects of pH on aquatic organisms?

20
Q

what are the effects on natural waters of aluminum?

21
Q

what is the speciation of aluminum?

22
Q

what is the aluminum in some lakes?

25
Q

what is the environmental toxicity of acid rain?

A

i. gas toxicity
-SO2
-NO2

ii. effects of acidity

26
Q

what is the gas toxicity of SO2?

27
Q

what is the gas toxicity of NO2?

28
Q

what are the effects of acidity?

29
Q

what are the effects on human health?

30
Q

what happened in southern china?

31
Q

what are the effects on structures?

32
Q

what does PM2.5 mean?

33
Q

what are the effects on structure of sulphation?

34
Q

what is the anode and the cathode?