lect 12 Flashcards
what are the limits of pE in water?
what are the applications of pE-pH diagrams?
what is the template for use with pE-pH plots?
what can humic substances react as?
humic substances as natural reductants?
-humic substances may function as reducing agents in natural water systems
-may be due to the quinone/hydroquinone group
what are measurements of pE? what are the limitations?
-indicator electrode (inert) develops potential in response to ratio of redox couples
-reference electrode
-voltmeter
limitations: non-equilibrium conditions, many species are part of several different redox couples… unstable potentials result
what is corrosion?
corrosion: destructive alteration of metal through interactions with its surroundings
when does corrosion take place?
what is the graph of the rusting of iron?
what is the graph of microbial corrosion such as of iron?