LE CHATLIER'S PRINCIPLE Flashcards

1
Q

Define le Chatelier’s principle. (1)

A

Le Chatelier’s Principle states that if a system in equilibrium is subjected to a change in concentration, temperature, volume, or pressure, the equilibrium will shift to counteract the imposed change, thus maintaining equilibrium.

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2
Q

why is Le Chatelier’s principle important? (1)

A

It helps predict how a system at equilibrium will respond to changes in its conditions and allows us to manipulate conditions to favour the desired reaction.

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3
Q

what are the key concepts when changing the concentration in an equilibrium mixture? (1)

A

Changes in concentration: If the concentration of a reactant or product is increased, the equilibrium will shift to consume or produce the added substance.

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4
Q

what are the key concepts when changing the pressure in an equilibrium mixture? (1)

A

Changes in pressure/volume: For gaseous reactions, an increase in pressure (or decrease in volume) will shift the equilibrium towards the side with fewer moles of gas.

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5
Q

what are the key concepts when changing the temperature in an equilibrium mixture? (1)

A

Changes in temperature: The effect of temperature change depends on whether the reaction is exothermic or endothermic.

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6
Q

what happens if you increase the concentration of the reactants in an equilibrium mixture? (1)

A

Increase in reactants: Equilibrium shifts towards products

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7
Q

what happens if you decrease the concentration of the reactants in an equilibrium mixture? (1)

A

Decrease in reactants: Equilibrium shifts towards reactants.

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8
Q

what happens if you decrease the concentration of the products in an equilibrium mixture? (1)

A

Decrease in products: Equilibrium shifts towards products.

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9
Q

what happens if you increase the concentration of the products in an equilibrium mixture? (1)

A

Decrease in reactants: Equilibrium shifts towards reactants.

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10
Q

what happens if you increase the pressure (decrease the volume) in an equilibrium mixture? (1)

A

Increase in pressure (decrease in volume): Equilibrium shifts towards the side with fewer moles of gas.

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11
Q

what happens if you decrease the pressure (increase the volume) in an equilibrium mixture? (1)

A

Decrease in pressure (increase in volume): Equilibrium shifts towards the side with more moles of gas.

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12
Q

what happens if you change the temperature of an exothermic reaction in an equilibrium mixture? (1)

A

Exothermic reaction (heat is released): Increasing temperature shifts equilibrium towards the reactants (left).

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13
Q

what happens if you change the temperature of an endothermic reaction in an equilibrium mixture? (1)

A

Endothermic reaction (heat is absorbed): Increasing temperature shifts equilibrium towards the products (right).

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14
Q

what are the characteristics of an exothermic reaction? (1)

A

exothermic reactions release heat to the surroundings.

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15
Q

what are the characteristics of an endothermic reaction? (1)

A

endothermic reactions absorb heat from the surroundings.

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16
Q

what effect does a temperature increase have on a exothermic reaction in an equilibrium mixture? (1)

A

Increasing temperature shifts equilibrium towards the reactants (left).

17
Q

what effect does a temperature increase have on a endothermic reaction in an equilibrium mixture? (1)

A

Increasing temperature shifts equilibrium towards the products (right).

18
Q

what effect does a temperature decrease have on a exothermic reaction in an equilibrium mixture? (1)

A

Decreasing temperature shifts equilibrium towards the products (right).

19
Q

what effect does a temperature decrease have on a endothermic reaction in an equilibrium mixture? (1)

A

Decreasing temperature shifts equilibrium towards the reactants (left).

20
Q

what effect does increasing the temperature of an exothermic reaction have on the Kc constant? (1)

A

K decreases with increasing temperature

21
Q

what effect does increasing the temperature of an endothermic reaction have on the Kc constant? (1)

A

K increases with increasing temperature.

22
Q

define the equilibrium constant. (1)

A

The equilibrium constant, denoted as K, is a numerical value that expresses the ratio of concentrations of products to reactants at equilibrium for a chemical reaction.