LE CHATLIER'S PRINCIPLE Flashcards
Define le Chatelier’s principle. (1)
Le Chatelier’s Principle states that if a system in equilibrium is subjected to a change in concentration, temperature, volume, or pressure, the equilibrium will shift to counteract the imposed change, thus maintaining equilibrium.
why is Le Chatelier’s principle important? (1)
It helps predict how a system at equilibrium will respond to changes in its conditions and allows us to manipulate conditions to favour the desired reaction.
what are the key concepts when changing the concentration in an equilibrium mixture? (1)
Changes in concentration: If the concentration of a reactant or product is increased, the equilibrium will shift to consume or produce the added substance.
what are the key concepts when changing the pressure in an equilibrium mixture? (1)
Changes in pressure/volume: For gaseous reactions, an increase in pressure (or decrease in volume) will shift the equilibrium towards the side with fewer moles of gas.
what are the key concepts when changing the temperature in an equilibrium mixture? (1)
Changes in temperature: The effect of temperature change depends on whether the reaction is exothermic or endothermic.
what happens if you increase the concentration of the reactants in an equilibrium mixture? (1)
Increase in reactants: Equilibrium shifts towards products
what happens if you decrease the concentration of the reactants in an equilibrium mixture? (1)
Decrease in reactants: Equilibrium shifts towards reactants.
what happens if you decrease the concentration of the products in an equilibrium mixture? (1)
Decrease in products: Equilibrium shifts towards products.
what happens if you increase the concentration of the products in an equilibrium mixture? (1)
Decrease in reactants: Equilibrium shifts towards reactants.
what happens if you increase the pressure (decrease the volume) in an equilibrium mixture? (1)
Increase in pressure (decrease in volume): Equilibrium shifts towards the side with fewer moles of gas.
what happens if you decrease the pressure (increase the volume) in an equilibrium mixture? (1)
Decrease in pressure (increase in volume): Equilibrium shifts towards the side with more moles of gas.
what happens if you change the temperature of an exothermic reaction in an equilibrium mixture? (1)
Exothermic reaction (heat is released): Increasing temperature shifts equilibrium towards the reactants (left).
what happens if you change the temperature of an endothermic reaction in an equilibrium mixture? (1)
Endothermic reaction (heat is absorbed): Increasing temperature shifts equilibrium towards the products (right).
what are the characteristics of an exothermic reaction? (1)
exothermic reactions release heat to the surroundings.
what are the characteristics of an endothermic reaction? (1)
endothermic reactions absorb heat from the surroundings.