Last Second Things Forgotten Flashcards
Group 2 bases
Agriculture and medicine
Ca (Oh)2 is limewater and used to neutikise acidic pH soils
Mg(oH2) 2 milk of magnesia used to treat indigestion by neutrilsing excess acid, soluble enough to get there but not soluble enough to pass into system
Iodine state at RTP
Trend of halogens going down
Is SOLID
Boiling increases due to more electrons thus more London etc
Reactivity of halogens going down
Halogen displacment reactiosn
Colours
Decreases, need to attract an electron, nuckear attraction decreases lower you go hence reactivity decreases
A more reactive halogen will displace a less, releasing that into solution
= chlorine green green
Iodine is orange then orange
Iodine is BROWN THEN VIOLET in organic solvent
How are acids from disportionation bleach show
Add indicator red then white
Advantages disadvantages of chlorine use with water
Kills bacteria which makes water safe to drink
However chlorine could end up reacting with hydrocarbons tk form chlorinated which are CARBIN one if AND TOXIC CHLORINE GAS
But clean water clear
Ammonia test
Ammonium ions to hydroxide ions, thr. Heat , damp paper, turns it red to blue
Ammonia used ti differniate silvers, where solubitliy decreases lower you go
Standard conditions
Temo is 25! 100 KPa , 1 Molsm conc
Enthlapy changes
Reaction
Formation
Combustjon
Neutiksiation
The enthlapy change that accompanies a reaction in its MOLAR quantities
Enthlapy change that accompanies the formation of ONE mole of product from constituent elements under standard etc
Enthlapy change that accompanies complete combustion of one mole of fuel under standard
Enthalpy change neutrilisation : the e enthlapy change that accompanies ONE MOLE OF water formation from acid and base etc, constant value around -57
Will have to divide / multiply moles accordingly
3 reasons less Exothermic
Tips to reduce?
Calculations “
Evaporation from wick
Incomplete combustjon
Heat loss to surroundings
All means more moles so less value
Non standard could could not
= use draught screens to block wind, oxygen canisters to ensure complete
Ensure all mass of what’s being heated up is used, and moles of what is required ( water, fuel, product) depending on enthaloy used
Average bond enthlapy
Limitations (2)
Energy required to break one mole of a specified type of bond in a gaseous molecule
1) average
2) defined at gaseous whereas most don’t take part at that
Hess law formation
Remember enthlapy of formation for an element is 0, for everything else clockwise = anti-clockwise
Combustjon down, formation up , else manipulate until achieve equation you want
Why is it hard to determine combustjon direclty?
- form so many other compounds that dozens of compounds formed impossible to measure , hence must be used indirectly Hess
Collision theory
Concentration = means more collisions , temp 2 , sa means more reactsnt moelcules exposed ti be reacted at any time so more collisions etc
Need to collide with correvt orientation , ea and collide, so often hard for one step reactiosn as unlikely this can happen, hence multi step
Effect of catalyst benefit disadvantage
Means companies need lower tempertaures and thus less energy, hence less fossil fuels burnt, hence less emissions and co2
HOWEVER some catalysts are toxic so must be considered, overall still better
Boltzmann ea temp
Ea means higher proptinal has ea
Increase temp means more molecules has old ea
Dynamic equilibrium
When rate of forward reavtion = rate of backward
Concentrations are the same
In a closed system
CALAYST increases rate of forward and backward but that’s it
How else to recycle and used polymers waste
What’s the problem with recycling PVC
1) combustion for fuel
2) organic feedstock for other processed and chemicals
1) has cl such that di used for fuel can produce HCl which is TOXIC
Why good biodegradable and how
Done as easilly hydrolysed by water
Means less waste, which is per meant normally, and also reducing dependency on finite resources
Alchol reactions
Carboxylic , acyl chlorides all to form esters
NABr + h2so4 to produce halolakne, where reaction happens in vitu ( can use hcl instead )
Oxidations calm
Dehydration with conc acid caltyst to form teo alchols, where major product is on markownikoff rule again
Rate of hydrolysis and test
Increases as carbon halogen bond decreases
Test with silver nitrate, aqeuous, and ethanol, which allows it to show
- hydrlysis occurs
- heat silver nitrate and separately ethanol and halolakne , and mix et
As STRENGHT kf bond decreases, easier to hydrolysed, greater rate
How to do colorimeter
Identity what changing colour
- use OPPSITE colour wavelength filter, and zero with water
- take freuwney samples of known conc and measure absorbsncd whatever
- then plot curve and uses this to find the conc , can use to make a conc time graph to find rates and also potential order