Chapter 2 Flashcards
How thingd measured in mass relatively? (DONT NEED TO KNOW)
Also what happened that means we can’t just measure the masses of protons electrons neutrons?
- standard isotope on which all atomic masses will be relative to is chosen as carbon 12
- Mass carbon 12 isotope is defined as exactly 12 atomic units (U)
- standard unit is one U which is 1/12th
- thus is roughly same mass as portion / neutron
2) mass defect, nucleus binds holding nucleus comes with a small decrease of mass (Einstein ) (don’t need to know)
Isotope definition
Atoms of the same elements with different number of neutrons and different masses
(Sam’s protons, different mass number due to different amount of neutrons)
Relative isotopic. Mass
Mass of an isotope relative with 1/12 of the mass of an atom of carbon 12
(Can assume it’s same as mass number if they don’t give )
Relative atomic mass
Weighted mean mass of an atoms of an element relative to the 1/12th of the mass an atom of carbon 12
Mass spectrometry
A
What does it mean by weighted mean mass (as part of relative atomic mass)
Weighted mean mass takes account if
- percentage abundance of Esch isotope
- the relative isotopic mass of each isotope
As in multiply abundance by each isotopic mass then divide by hundred, takes in account of these
What is mass spectrometry used for
2 Pints
- determination of relative isotopic masses and relative abundances of each isotope (so Esch mass and then how abundant it is and then
- calculation of relative atomic mass of an element from the relative abundance of its isotope
- determination of relative isotopic masses and relative abundances of each isotope (so Esch mass and then how abundant it is and then
(All of the masses and their abundsncies are avaegrad out based on percentages to make relative atomic mass)
How to work relative atomic mass by hand
Multiply each mass by the percentage (M/ RSTIO ON HRAPH)
Add
Divide by hundred
What is m/z (kinda important)
If charge of ion is plus 1, m/z is same mass of ion which is same mass of element too
Atom
What do a and z represent
Deuterium ?
- nucleus protons neutrons, electrons in shells
- electron 1/1836 mass of proton
- neutrons is glue between atom holding the nucleus together a s protons repel (waffle)
- z number of protons , a protons and neutrons
3) deuterium is just 2/1 hydrogen, with a neutron, and heavy water is D2O. As more heavy isotope boiling melting density increase
Isotopes change Physical but not chemical reactions how?
Chemical reactions depend on electrons surrounding nucleus, but electrons are constant
Higher mass isotopes will have higher melting boiling snd density tho
Charge on Zn and Ag
Zn+2 , Ag+1
Binary compund
Contains two elements only
Polyatomic SHANC
Sulfate SO4 2- Hydorixide OH- Amomminum NH4+ Nitrate = No3 - Carbonate = CO3-2
4 are sulfate and ammonium
Nitrite sulfide?
Same charge one less oxygen due to “ite”
= NO2-
= SO3-2