Key Terms Unit 1 Flashcards
Oxidation Number
Is the number of electrons that need to be added to or removed from an element to make it neutral
Atomic Number
Is the number of protons in the nucleus of an atom
Mass Number
Is the number of protons and neutrons in the nucleus of an atom
Isotopes
Are atoms that have the same number of protons but different numbers of neutrons
Ion
Is a particle where the number of electrons does not equal the number of protons
α - particles
Have a nucleus of two protons and two neutrons, therefore positively charged
β - particles
Are fast moving electrons, therefore negatively charged
γ - rays
Are high energy electromagnetic radiation, therefore no charge
Half-life
Is the time taken for the atoms in a radioisotope to decay, or the time take for the radioactivity of a radioisotope to fall to half its initial value
Atomic orbital
Is a region in an atom that can hold up to two electrons with opposite spins
First Ionisation Energy
Is the energy required to remove one electron from each atom in one mole of its gaseous atoms
Shielding Effect
Is the repulsion between electrons in different shells. Inner shell electrons repel outer shell electrons
Successive Ionisation Energies
Are a measure of the energy need to remove each electron in turn until all the electrons are removed from an atom
Convergence Limit
Is when spectral lines become so close together they have continuous band of radiation and separate lines cannot be distinguished
Relative Atomic Mass
Is the average mass of one atom of the element relative to one-twelfth the mass of one atom of carbon-12
Relative Isotopic Mass
Is the mass of an atom of an isotope relative to one-twelfth the mass of an atom of carbon-12
Relative Formula Mass
Is the sum of the relative atomic masses of all atoms present in the formula
Molecular Ion
Is a positive ion formed in a mass spectrometer from the whole molecule
Fragmentation
Is splitting of molecules, in a mass spectrometer into smaller parts
One Mole
Is the amount of any substance that contains the same number of particles as there are atoms in 12g of carbon-12
Avogadro Constant
Is the number of atoms per mole
Molar Mass
Is the mass of one mole of a substance
Stoichiometry
Is the molar relationship between the amounts of reactants and products in a chemical reaction
Empirical Formula
Is the simplest formula showing the simplest whole number ratio of the number of atoms of each element present
Molecular Formula
Shows the actual number of atoms of each element present in the molecule it is a simple multiple of the empirical formula
Molar Volume, Vm
Is the volume per mole of a gas, (given on data sheet)
Atom Economy
Is the percentage of Mass of reactants divided by total mass of reactants
Percentage Yeild
Is the percentage of Mass of product obtained divided by Maximum theoretic mass
Ionic Bond
Is a bond formed by the electrical attraction between positive and negative ions
Covalent Bond
Has a pair of electrons with opposed spin shared between two atoms with each atom giving one electron
Coordinate Bond
Is a covalent bond in which both electrons are shared by one of the atoms
Electronegativity
Is a measure of the electron-attracting power of an atom in a covalent bond
Polar Bond
Has one end of the bond with a slightly positive charge and the other end with a slightly negative charge
Intermolecular Bonding
Is the weak bonding holding the molecules together, and governs the physical properties of the substance
Intramolecular Bonding
Is the strong bonding between atoms in the molecule, and governs its chemistry
Van Der Waals Forces
Include all types of intermolecular force whether dipole or induced dipole
The Coordination Number
Of an ion gives the number of its nearest neighbours
Delocalised
Means that an electron is not attached to a particular atom
Volatility
Describes how readily a substance vaporises
Reversible Reaction
Is one that can go in either direction depending on the conditions
Dynamic Equilibrium
Is when the forward and reverse reactions occur at the same rate
Position of Equilibrium
Is the proportion of products to reactants in an equilibrium mixture
Le Chatelier’s Principle
States that if a system at equilibrium is subjected to a change, the equilibrium tends to shift so as to minimise the effect of the change
Acid
Is a proton donor
Base
Is a proton acceptor
Strong Acid
Is one that full dissociates in aqueous solution
Weak Acid
Is one that partially dissociates in aqueous solution
Salt
Is the compound that forms when a metal ion replaces the hydrogen ion in an acid
Standard Solution
Is one for which the concentration is accurately known