Kc and Kp Flashcards

1
Q

What is Kc in terms of?

A

Equilibrium concentrations

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2
Q

What is Kc dependant on?

A

Temperature

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3
Q

What is Kc?

A

A constant

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4
Q

What does a value of 1 for Kc tell you?

A

Position of equilibrium is halfway between reactants and products

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5
Q

What does a value of >1 for Kc tell you?

A

Position of equilibrium is towards the products

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6
Q

What does a value of <1 for Kc tell you?

A

Position of equilibrium is towards the reactants

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7
Q

What does the larger the value of Kc mean?

A

The further the position lies to the right so the greater the concentration of products compared to the reactants

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8
Q

What does the square brackets of Kc and Kp mean?

A

“Concentration of”

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9
Q

What does a,b,c,d of Kc and Kp mean?

A

Balancing numbers in the equation

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10
Q

What does A,B,C,D of Kc and Kp mean?

A

Equilibrium concentrations

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11
Q

What is different between Kc and Kp?

A

Kp is for gaseous equilibrium

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12
Q

What does the p mean in Kp?

A

Partial pressure

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13
Q

What is Kp dependent on?

A

Temperature

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14
Q

What is the equation for partial pressure?

A

Mole fraction X total pressure

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15
Q

What must the mole fraction add up to?

A

1

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16
Q

What must the partial pressure add up to?

A

The total pressure

17
Q

What type of calculation must you use when calculating Kp?

A

ICE calculations

18
Q

Describe an ice calculation

A

Initial moles - products always have 0 initial moles
Change
Equilibrium moles
Equilibrium concentration

19
Q

When will K only change?

A

When you change temp

If you change pressure, conc or use a catalyst K will only change if temp also changes

20
Q

What happens to K when temp increases (exo)?

A

K decreases

Equilibrium shifts to the left

21
Q

What happens to K when temp decreases (endo)?

A

K increases

Equilibrium shifts to the right

22
Q

Why does Le Chatelier’s Principle only work?

A

As K controls the relative conc of reactants + products at equilibrium to maintain a constant value

23
Q

What happens if you increase the pressure?

A

Increase of pressure shifts to side with fewest molecules of gas
So to return Kp back must increase reactant + decrease product
So equilibrium shifts left

24
Q

What happens if you increase pressure on ammonia production?

A

Conc of everything increases
So value of Kc decreases as conc increases
To restore Kc must increase reactants + decrease products

25
Q

How do you restore Kp if you increase the temp?

A

Must decrease the reactants + increase the products

26
Q

Are equilibrium constants affected by catalysts?

A

NO

27
Q

What do catalysts do?

A

Affect rate of reaction but not equilibrium position