Equilibrium Flashcards

1
Q

What is dynamic equilibrium?

A

When the rate of the forward reaction is the same as the backwards reaction. Concentration of reactions + products remain constant

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2
Q

What is the general equation for dynamic equilibrium?

A

A + B —> C + D

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3
Q

What is Le Chatelier’s Principle?

A

When a system in equilibrium is subjected to an external change the system readjusts itself to minimise the effect of that change

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4
Q

What would happen if you increased the concentration of reactants/products in equilibrium?

A

Equilibrium position would shift to the other side

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5
Q

What would happen if you decreased the concentration of reactants/products in equilibrium?

A

Equilibrium position would shift to the other side

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6
Q

What would happen if you increased the temperature of a reaction in equilibrium?

A

Equilibrium position would shift in the endothermic direction

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7
Q

What would happen if you decreased the temperature of a reaction in equilibrium?

A

Equilibrium position would shift in the exothermic direction

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8
Q

What would happen if you increased the pressure of a reaction in equilibrium?

A

Equilibrium position would shift in the side with the fewest moles of gas

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9
Q

What would happen if you decreased the pressure of a reaction in equilibrium?

A

Equilibrium position would shift in the side with the most moles of gas

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10
Q

What effect does catalysts have on the equilibrium position?

A

NONE

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11
Q

How do the rate of the forwards and reverse reaction increase?

A

By the same amount

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12
Q

What does enthaply change tell you in equilibrium reaction?

A

The reaction type of the forwards reaction

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13
Q

What happens when it shifts to the right?

A

MORE PRODUCTS

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14
Q

What is the equation for the Haber process?

A

N2(g) + 3H2(g) —-> 2NH3(g)

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15
Q

What can Le Chatelier’s Principle be used to predict?

A

The best conditions needed to force the equilibrium to the right in order to produce the maximum yield

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16
Q

Why would you not use a low temperature in the Haber process?

A

Produce a high yield but at a very slow rate

17
Q

Why would you not use a high pressure in the Haber process?

A

Safety issues

Needs lots of energy

18
Q

What type of conditions does the Haber process normally operate under?

A

Compromise conditions

19
Q

What would using a high enough temperature ensure in the Haber process?

A
Reasonable rate without shifting equilibrium
Good yield
Quick
Cheap
Safe
20
Q

What are the conditions for the Haber process?

A

300-350 degrees
100-200 atm
Iron catalyst

21
Q

What does the iron catalyst do in the Haber process?

A

Speed up the reaction so a lower temperature can be used

22
Q

What is the yield percentage for the Haber process?

A

15%

23
Q

What happens to the unreacted hydrogen and nitrogen in the Haber process?

A

Repeatedly recycled back into the process

24
Q

How is the exact position of equilibrium calculated?

A

Using equilibrium law