Ionisation Energies 1.1 4 Flashcards

1
Q

Electrons move to higher energy levels

A

Atoms in the gaseous state are given energy by heating or passing an electric current through them

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2
Q

Emit electromagnetic Radiation

A

Return back to lower energy levels . Analyse electromagnetic radiation emitted by a device called a spectroscope

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3
Q

Specific frequencies emitted

A

Unique to an individual element

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4
Q

Emission spectrum produced

A

A line spectrum

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5
Q

Only certain frequencies of electromagnetic radiation emitted

A

Evidence that energy of electrons in atoms only have certain fixed values

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6
Q

Ionisation energy

A

Energy to completely remove an electron of an atom

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7
Q

Successive ionisation energies

A

Steady increases , big jumps - evidence for the existence of quantum shells

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8
Q

First quantum shell

A

Have the lowest energy so require the most energy to remove

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9
Q

Electron lost in ionisation

A

So far from the influence of the nucleus that it no longer experiences the attractive force of the nucleus - infinite distance

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10
Q

Ionisation energy depends on

A

Energy has when it is in its orbital within an atom

Ionisation energy =energy of electron when removed - energy of electron when in orbital

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11
Q

Electron - electron repulsion

A

Within orbital shield from effect of nuclear charge

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12
Q

Factors affect energy of an electron spectrum

A

Orbital in which the electron excists
Nuclear charge of the atom
Repulsion shielding experiences by the electrons from all other electrons present

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13
Q

Across a period

A

nuclear charge increases as the number of protons increase
electron is added to same quantum shell increase energy of outermost electron
nuclear charge more significant so general increase in first ionisation energy
not perfect trend

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14
Q

Down a group

A

nuclear charge increase as the number of protons increase decrase energy of outer electron
new quantum shell added on each occasion -increase energy of outermost electron as each qunatum shell has a higher energy than the other and outer electron experinces incrased shielding from inner electrons
first ionisation energy decreases
again faults

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15
Q

first ionisation energy definiton

A

energy required to remove an electron from each atom in a mole of atoms in the gaseous state

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16
Q

second ionisation energy

A

energy required to remove an electron from each singly charge positive ion in one mole of positive ions in the gaseous state