Ionisation Energies 1.1 4 Flashcards
Electrons move to higher energy levels
Atoms in the gaseous state are given energy by heating or passing an electric current through them
Emit electromagnetic Radiation
Return back to lower energy levels . Analyse electromagnetic radiation emitted by a device called a spectroscope
Specific frequencies emitted
Unique to an individual element
Emission spectrum produced
A line spectrum
Only certain frequencies of electromagnetic radiation emitted
Evidence that energy of electrons in atoms only have certain fixed values
Ionisation energy
Energy to completely remove an electron of an atom
Successive ionisation energies
Steady increases , big jumps - evidence for the existence of quantum shells
First quantum shell
Have the lowest energy so require the most energy to remove
Electron lost in ionisation
So far from the influence of the nucleus that it no longer experiences the attractive force of the nucleus - infinite distance
Ionisation energy depends on
Energy has when it is in its orbital within an atom
Ionisation energy =energy of electron when removed - energy of electron when in orbital
Electron - electron repulsion
Within orbital shield from effect of nuclear charge
Factors affect energy of an electron spectrum
Orbital in which the electron excists
Nuclear charge of the atom
Repulsion shielding experiences by the electrons from all other electrons present
Across a period
nuclear charge increases as the number of protons increase
electron is added to same quantum shell increase energy of outermost electron
nuclear charge more significant so general increase in first ionisation energy
not perfect trend
Down a group
nuclear charge increase as the number of protons increase decrase energy of outer electron
new quantum shell added on each occasion -increase energy of outermost electron as each qunatum shell has a higher energy than the other and outer electron experinces incrased shielding from inner electrons
first ionisation energy decreases
again faults
first ionisation energy definiton
energy required to remove an electron from each atom in a mole of atoms in the gaseous state