17.2 1 Carbonyl compounds and their physical properties Flashcards

1
Q

carbonyl group

A

C=0

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2
Q

Two carbonyl compounds

A

aldehydes and kentones

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3
Q

how to name aldehydes

A

-al e.g butanal

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4
Q

aldehyde

A

if h attached

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5
Q

ketone

A

no h

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6
Q

naming kentone

A

one e.g pentan-2-one

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7
Q

bond

A

combination of sigma and pi polar as different atoms involved greater electron density nearer the oxygen atoms

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8
Q

aldhydes scent

A

shorter unpleasant solvent smell.

longer pleasant rose smell

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9
Q

lower ketones

A

solvent smell

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10
Q

aldehydes and ketones boiling points

A

permanent dipole-dipole attractions
no hydrogen bonding because all hydrogen is joined to carbon atoms
Boiling temperatures increase with molar mass as the extent of London forces increase
have inter-molecular forces of an intermediate strength

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11
Q

At room temperature

A

methanal is a gas all the others are liquid

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12
Q

solubility in water

A

lower aldehydes and ketones are soluble in water because they can form hydrogen bonds with slightly negative O
solubilty decreases with increasing chain length as the hydrocarbon part of the molecules becomes more significant

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