17.2 1 Carbonyl compounds and their physical properties Flashcards
carbonyl group
C=0
Two carbonyl compounds
aldehydes and kentones
how to name aldehydes
-al e.g butanal
aldehyde
if h attached
ketone
no h
naming kentone
one e.g pentan-2-one
bond
combination of sigma and pi polar as different atoms involved greater electron density nearer the oxygen atoms
aldhydes scent
shorter unpleasant solvent smell.
longer pleasant rose smell
lower ketones
solvent smell
aldehydes and ketones boiling points
permanent dipole-dipole attractions
no hydrogen bonding because all hydrogen is joined to carbon atoms
Boiling temperatures increase with molar mass as the extent of London forces increase
have inter-molecular forces of an intermediate strength
At room temperature
methanal is a gas all the others are liquid
solubility in water
lower aldehydes and ketones are soluble in water because they can form hydrogen bonds with slightly negative O
solubilty decreases with increasing chain length as the hydrocarbon part of the molecules becomes more significant