[🧪] Hydrocarbons Flashcards
What are the two ways for dehydration of alcohols into alkenes?
- dehydration using heated Al₂O₃ catalyst
- dehydration using concentrated H₂SO₄
Production of alkenes
Define
cracking
14 Hydrocarbons
the breaking down of large chain alkanes into smaller chain alkanes and alkenes
14 Hydrocarbons
General equation for dehydration of alcohols to alkenes
CnH2n+1OH → CnH2n + H₂O
Significance of alkenes’ π bonds
- it’s an area of high electron density
- pi electrons make the molecule more susceptible to attacks by e- deficient groups like electrophiles
Define
electrophile
a species that is deficient in electrons
eg: positive ions (H+ in HCl)
Define
electrophillic addition
the addition of an electrophile to a double bond
3 methods of producing alkenes
- cracking of long chain hydrocarbons (Al₂O₃ catalyst and high temperature)
- dehydration of alcohols (heated Al₂O₃ catalyst / concentrated H₂SO₄)
- elimination of halogenoalkane (ethanollic NaOH and heat)
Elimination reaction of halogenoalkane to form alkene
R—X + NaOH → Alkene + H₂O + NaX
What is the mechanism for
halogenation of alkanes
free-radical substitution
Define
functional group
an atom or a group of atoms in an organic molecule, which determines the physical and chemical properties of the molecule