how far? Flashcards

1
Q

what does it mean when a reaction is at equilibrium?

A

the rate of the forward and reverse reactions are equal

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2
Q

what are the methods that can be used to measure equilibrium

A
  • measure the change in colour or colour intensity using colourimeter
  • use a pH probe
  • measure electrical conductivity
  • titration (when equilibrium is slow so that titration can be completed before there is much change in e
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3
Q

what does mole fraction mean?

A

the amount of a given component in a given reaction mixture

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4
Q

state the equation used to calculate mole fractions

A

mole fraction = number of moles of substance A / total number of moles of all substances

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5
Q

what does partial pressure mean

A

the pressure exerted by a single species in a reaction vessel

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6
Q

what is the symbol for partial pressure

A

P

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7
Q

state the equation used to calculate the partial pressure

A

partial pressure = mole fraction x total pressure

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8
Q

what is the relationship between the concentration of a substance and its partial pressure?

A

concentration of a substance is proportional to its partial pressure

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9
Q

what are the 3 common units of pressure used in chemistry?

A
  • pascals (Pa)
  • atmospheres (atm)
  • newtons per square metre
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10
Q

what type of brackets are used in Kc expressions?

A

square [ ]

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11
Q

what type of brackets are used in Kp expressions?

A

round ( )

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12
Q

a reaction has the equation:

aA(g) + bB(g) -> cC(g) + dD)g)

what is its Kp expression?

A

Kp = p(Cc) p(Dd) / p(Aa) p(Bb)

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13
Q

what is the symbol of the equilibrium constant?

A

K

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14
Q

what does it mean when K is greater than 1?

A

reaction favours product

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15
Q

what does it mean when K is less than 1?

A

the reaction favours reactants

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16
Q

what is the effect of increasing temperature on K?

A

equilibrium shifts to the direction of the endothermic reaction

17
Q

what is the effect of decreasing temperature on K?

A

equilibrium shifts to the direction of the exothermic reaction

18
Q

what is the only factor that affects K?

A

temperature

19
Q

what is the effect of increasing temperature on K for a forward endothermic reaction?

A

K increases as temperature increases

20
Q

what is the effect of increasing k for a forward exothermic reaction?

A

K decreases as temperature increases

21
Q

what effect does the catalyst have on K?

A

catalysts don’t have an effect on the position of the equilibrium

they only affect the rate of reaction