group 2 and 7 Flashcards

1
Q

What is a common name given to group 2 metals

A

Alkaline earth metals

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2
Q

What is the most reactive metal of group 2

A

Barium

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3
Q

List 3 physical properties of group 2 metals

A
  • High melting and boiling points
  • Low-density metals
  • Form colourless (white) compounds
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4
Q

What ions does group 2 form in redox reactions?

A

Group 2 lose their two outer electrons to form 2+ ions

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5
Q

The highest energy electrons of group 2 metals are in which subshell?

A

S-subshell

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6
Q

What are the relative reactivities of Group 2 elements in redox reactions with oxygen

A

When group 2 metals are burnt in oxygen, they form solid white oxides.

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7
Q

What are the relative reactivities of Group 2 elements in redox reactions with water

A

The group 2 metals react with water to give metal hydroxide and a hydrogen gas

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8
Q

What are the relative reactivities of Group 2 elements in redox reactions with dilute acids

A

When group 2 metals react with dilute hydrochloric acid, you get a metal chloride and hydrogen gas

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9
Q

What is the trend of reactivity down group 2 metals

A
  • Reactivity increases

- Electrons are lost more easily because larger atomic radius and more shielding

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10
Q

What is the trend in first ionisation energy down group 2

A
  • Decreases
  • Because electron number increases so shielding increases
  • Increases atomic radius so there are weaker nuclear forces
  • So less energy is needed to remove the electron
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11
Q

Which group 2 element reacts very slowly with water?

A

Magnesium

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12
Q

What type of reaction is the reaction between group 2 elements and oxygen?

A

Redox reaction

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13
Q

What type of reaction is the reaction between group 2 metals and water?

A

Redox reaction

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14
Q

What is oxidised and what is reduced in a reaction between group 2 metal and water?

A
  • Metal is oxidised

- One hydrogen atom from each water is reduced

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15
Q

What group 2 metal oxide is insoluble in water?

A

Beryllium oxide

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16
Q

What is the trend in hydroxide solubility down group 2?

A
  • Increases down the group
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17
Q

What is the use of Ca(OH)2

A

Used to neutralise soil

18
Q

What is the use of Mg(OH)2

A
  • Antacid to treat indigestion
19
Q

What is calcium carbonate used for

A
  • Present in limestone and marble

- Used in building construction

20
Q

List 2 properties of halogens

A
  1. Low melting and boiling point

2. Exist as diatomic molecules

21
Q

Explain the trend in the boiling group down group 7

A
  • Increases down the group
  • Because size of the atom increases as more occupied shells
  • Stronger London forces of attraction between molecules, take more energy to overcome
22
Q

Explain the trend in reactivity down group 7

A
  • Reactivity decreases
  • Because atomic radius increases
  • Electron shielding increases
  • Ability to gain an electron and form -1 ions decreases
23
Q

Explain the trend in oxidising ability down the group

A
  • Decreases down the group
  • Cl has the fewest occupied electron shells, and greatest nuclear attraction so it is easiest to gain electrons and be reduced
24
Q

Explain the trend in reducing the ability of the halides down the group

A
  • Increases down the group
  • Iodine has the most occupied electron shells so outer electrons are further from the nucleus, and is the easiest to be oxidised and lose electrons
25
What is the colour of chlorine in water
Pale green
26
What is the colour of bromine in water
Orange
27
What is the colour of iodine in water
Brown
28
What is the colour of chlorine in cyclohexane
Pale green
29
What is the colour of bromine in cyclohexane
Orange
30
What is the colour of iodine in cyclohexane
Violet
31
Define disproportionation
When an element is oxidised and reduced at the same time in a redox reaction
32
What type of reaction is the reaction of chlorine with water
Disproportionation
33
Why is chlorine added to drinking water
It kills the bacteria in the water and makes it safer to drink
34
What is the equation for forming bleach?
Cl2 + 2NAOH -> NaCl + NaClO + H2O
35
What is the formula of bleach
NaClO
36
What kind of molecules do halogens exist as?
Diatomic molecules
37
How can you see the colour change in a displacement reaction with halogens?
By adding an organic solvent like hexane, it settles out a distinct layer above the aqueous solution
38
Describe the test for halides
1. Add dilute nitric acid 2. Add silver nitrate solution 3. A precipitate of the silver halide is formed 4. Test results by adding ammonia solution
39
What is observed in the silver test for halides if a chloride ion is present?
- Precipitate colour: white | - Solubility in ammonia: dissolved in dilute NH3
40
What is observed in the silver test for halides if a bromide ion is present?
- Precipitate colour: Cream | - Solubility in ammonia: dissolves in concentration
41
What is observed in the silver test for halides if an iodide ion is present?
- Precipitate colour: Yellow | - Solubility in ammonia: insoluble in concentration
42
What are the alternatives to using chlorine in water and explain them?
1. Ozone - A strong oxidising agent which makes it good for killing microorganisms, its expensive to produce and has a short-half life so it's treatment isn't permanent 2. Ultraviolet light - It kills microorganisms by damaging their DNA, it is ineffective in cloudy water and it won't stop the water from being contaminated further down