halogens in environment Flashcards
ozone layer
outer edge of earth stratosphere
absorbs UV-B radiation from sun rays
effects of ozone depletion
increased skin/ genetic damage
greater risk of skin cancer
effect of UV
breaks C-H bond by homolytic fission to form radicals
photodissociation
radiation initiating break down
break down of ozone
Propagation 1: Cl* + O3 → ClO* + O2
Propagation 2: ClO* + O→ Cl* + O2
Overall: O3
+ O → 2O2
chlorine radical may go on in chain reaction
other radicals
NO formed by lightning strikes
NO* + O3 → NO2 * + O2
NO2* + O → NO* + O2
Overall O3
+ O → O2
research into alternatives to CFCs
coolants using hydrocarbons, ammonia or CO2 produced
organobromine problems
suspected to release toxins that may interfere with endocrine system in humans