Group 7, the Halogens: Uses of Chlorine and Chlorate(I) Flashcards

1
Q

What type of reaction occurs when chlorine reacts with cold water or sodium hydroxide?

A
  • Disproportionation reaction
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2
Q

Define the term disproportionation

A
  • A reaction in which the same element is simultaneously oxidised and reduced
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3
Q

Give the symbol equation for the reaction between chlorine and cold water, including state symbols

A
  • Cl2 (g) + H2O (l) ⇌ 2H+ (aq) + Cl- (aq) + ClO- (aq)
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4
Q

Explain how the reaction between chlorine and cold water is a disproportionation reaction

A
  • Cl2 (g) + H2O (l) ⇌ 2H+ (aq) + Cl- (aq) + ClO- (aq)
  • Cl2 OS is 0
  • Cl- OS is -1
  • ClO- OS is +1
  • Cl is both oxidised and reduced
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5
Q

Give the symbol equation for the reaction between chlorine and water in sunlight, including state symbols

A
  • 2Cl2 (g)+ 2H2O (l) → 4HCl (aq) + O2 (g)
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6
Q

Why is chlorine an effective water treatment?

A
  • Chlorate(I) ions kill bacteria
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7
Q

What is the downside of using chlorine to treat water?

A
  • Chlorine is toxic
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8
Q

Why is chlorine still used to treat water?

A
  • The benefits of killing bacteria outweigh the risks of the toxic chlorine
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9
Q

What is produced when chlorine gas is reacted with sodium hydroxide?

A
  • Sodium chlorate(I) solution (NaClO)
  • Common household bleach
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10
Q

Give the symbol equation for the reaction between sodium hydroxide and chlorine, including state symbols

A
  • 2NaOH (aq) + Cl2 (g) → NaClO (aq) + NaCl (aq) + H2O (l)
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11
Q

Explain why the reaction between sodium hydroxide and chlorine is a disproportionation reaction

A
  • 2NaOH (aq) + Cl2 (g) → NaClO (aq) + NaCl (aq) + H2O (l)
  • Cl2 OS is 0
  • NaClO OS is +1
  • NaCl OS is -1
  • Cl is both oxidised and reduced
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12
Q

What are the uses of sodium chlorate(I) solution?

A
  • Used in water treatment
  • Bleach paper and textiles
  • Cleaning toilets
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