Group 2 Flashcards

1
Q

When a group 2 metal react with water what is produced and what does the vigour depend on?

A

Metal hydroxide and hydrogen
Vigour -
-how easily two electrons are removed from the atom
-how. Soluble the hydroxides of metals are= reactivity increases down the group

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2
Q

What happens with solubility of Group 2 sulfates going down the group?

A

Decreases down the group
MgSO4-soluble
CaSO4-sparingly soluble
SrSO4 and Ba4-insoluble

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3
Q

Describe the precipitates you will see with Group 2 sulfates?

A

Mg =no ppt formed
Ca=faint white ppt
Ba , Sr=thick white ppt formed

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4
Q

Describe how to test for sulfate ions?

A

-1cm^3 of aq BaCl and 1cm^3 of dilute HCL\
-unknown solution with have a thick white ppt and it will not dissolve in dilute hcl

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5
Q

What is the role of HCl in test for sulfate ions?

A

Removes any other ions e.g Carbonates or OH

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6
Q

What are the solubilities of Group 2 hydroxides?

A

Increase down the group
-Mg(OH)2=insoluble
-Ca(OH)2=sparingly soluble
-Sr(OH)2 and Ba(OH)2=soluble

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7
Q

Describe the precipitates you will see with Group 2 hydroxides?

A

-Mg=white ppt
-Ca=faint white ppt
-Sr and Ba=no reactions

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8
Q

What is a use of Mg(OH)2?

A

Milk of magnesia= alleviate constipation

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9
Q

what is the use of Ca(OH)2?

A

Slaked lime to neutralise acidic soil

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10
Q

What is a use of BaSO4?

A

Barium meal , barium is good at absorbing X rays and is harmless as BaSO4 is insoluble

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11
Q

Describe how Titanium is extracted?

A

-Using two magnesium
2Mg + TiCl4 -> 2MgCl2 +Ti

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12
Q

What is a use of CaO and CaCO3?

A

Flue Gas Desulfurisation

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13
Q

What are the steps in Flue Gas Desulfurisation?

A

-CaO + SO2 + 2H2O -> CaSO3 + 2H2O
-CaCO3 + SO2 + 2H2O -> CaSO3 + 2H20 +CO2

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14
Q

What happens to the reactivity of Group 2 elements going down?

A

Reactivity increases as the electrons are lost more easily

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15
Q

What happens to the ionic radius of Group 2 elements going down?

A

It increases going down as there is a lower charge density so a weaker attraction

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16
Q

What happens to the first ionisation energy of Group 2 elements going down?

A

decreases as there is more shielding

17
Q

What is more alkali Mg(OH)2 or Ca(OH)2 and why?

A

Ca(OH)2 as it is more soluble