Electrode Potentials & Electrochemical cells Flashcards

1
Q

Why is platinum used as an electrode?

A

As it is inert (unreactive) and electrically conductive

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2
Q

What are the standard conditions of the standard hydrogen electrode?

A

Concentration - 1moldm-3
Temperature - 298K
Pressure - 100KPa

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3
Q

What side is hydrogen always on a cell diagram?

A

Left hand side

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4
Q

What will the electrode potential be when the negative electrode is on the left and positive is on the right?

A

Positive

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5
Q

What will the electrode potential be when the negative electrode is on the right and positive is on the left?

A

Negative

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6
Q

How is a cell diagram written?

A

Reduced form|Oxidised form||Oxidised form|reduced form

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7
Q

What does two lines mean on a cell diagram?

A

Salt bridge

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8
Q

What does one line on a cell diagram mean?

A

Physical state change

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9
Q

In terms of standard electrode potentials which values are more reactive?

A

More negative

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10
Q

What does the standard electrode potential show about the position of equilibrium?

A

The more positive the further it is to the right

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11
Q

What do all feasible reaction have in terms of electrode potentials?

A

Positive value

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12
Q

What are the three types of commercial cells?

A

-Non rechargeable (irreversible reaction)
-Rechargeable (reversible reaction)
-Fuel cells (generate electricity)

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13
Q

Give an example of a non rechargeable cell?

A

Zinc-Carbon cell

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14
Q

What are the advantages & disadvantages of zinc-carbon cells (non-rechargeable cells)?

A

-cheap to produce
-short life

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15
Q

Give an example of a rechargeable cell?

A

Lithium ion (Li-ion)

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16
Q

What reaction occurs at the negative electrode in a Li-ion cell?

A

Li → Li+ + e-

17
Q

What reaction occurs at the positive electrode in a Li-ion cell?

A

Li+ + CoO2 + e- → Li+[CoO2]-

18
Q

What is the electrochemical series?

A

List of electrode potentials in numerical order

19
Q

Why might a commercial cell have a different EMF value?

A

The reaction is not under standard conditions

20
Q

What is done to maintain the EMF value of a cell?

A

Constantly add reactants or keep their concentration constant

21
Q

What is the purpose of a salt bridge?

A

-Completes the circuit
-Allows ions to transfer