Alcohols Flashcards
What catalyst is used in the dehydration of alcohols?
Sulfuric acid (H2SO4)
What are the two ways alcohols are formed?
-Hydration of an alkene
-Fermentation
What does biofuel mean?
A fuel derived from living matter
What is the optimum temperature for fermentation?
30-40°C
What are the conditions for the hydration of alkenes?
conc Phosphoric acid
300°C
60atm
What are the equations for fermentation?
6CO2 + 6H2O → C6H12O6 + 6O2
C6H12O6 → 2C2H5OH + 2CO2
C2H5OH + O2 → 2CO2 + 3H2O
What are the disadvantages of biofuels?
-Requires alot of land to grow crops → reduces biodiversity
-Land could be used to grow food we can eat
-Engines have to be converted which is expensive
What is a positive result for Fehlings?
Brick red ppt
What is a positive result for Tollens reagent?
Silver mirror
What is used to oxidise alcohols?
Potassium dichromate/ K2Cr2O7 / [O]
What colour change does potassium dichromate when it reacts with 1°,2 ° & 3 ° alcohol?
-Primary: orange → green
-secondary: orange → green
-Tertiary: no change
How do you form a carboxylic acid?
Primary alcohol with potassium dichromate under reflux (with sulfuric acid)
How do you form an aldehyde?
Primary alcohol with potassium dichromate using distillation (with sulfuric acid)
How do you form a ketone?
Secondary alcohols with potassium dichromate under reflux (with sulfuric acid)