Exam 5 Flashcards

1
Q

Kinetic energy

A

Energy of motion

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2
Q

Potential energy

A

Stored energy

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3
Q

SI unit of energy

A

Joule

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4
Q

First law of thermodynamics

A

energy cannot be created or destroyed; it can only be converted from one form to another

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5
Q

state function

A

the only part that matters is the start and the end, not the steps of how you got there

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6
Q

energy is a ________ function

A

state

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7
Q

what does + heat mean in a reaction

A

endothermic (heat in)

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8
Q

what does (-) heat mean in a reaction

A

exothermic (heat out)

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9
Q

Endothermic (sign?)

A

heat in (+)

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10
Q

Exothermic (sign?)

A

heat out (-)

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11
Q

what does C stand for

A

Heat capacity

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12
Q

what does Cs stand for

A

Specific heat capacity

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13
Q

q (heat) = (is pretty much the same as)

A

ΔH Enthalpy (at constant pressure)

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14
Q

ΔHrxn = ΔHfinal - ΔHinitial

A
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15
Q

Hess’s Law

A

enthalpies are additive

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16
Q

Standard state conditions

A

P = 1 atm
T = 25°
Concentration = 1M

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17
Q

1atm = ? mmHg
1atm = ? Torr

A

760 mmHg
760 Torr

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18
Q

ΔH°f

A

Enthalpy of formation

19
Q

Enthalpy of formation

A

The energy required to form 1 mol of a substance from its elements in their standard state

20
Q

Calorimetry

A

the process of measuring the amount of heat released or absorbed during a chemical reaction

21
Q

Pressure

A

the force exerted by molecules on or against another body

22
Q

SI unit for pressure

A

atm

23
Q

what are the 4 simple gas laws

A

Boyles law, Charles law, Avogadro’s law, Daltons law

24
Q

Boyles law
(proportionality?)

A

P and V are related
(at constant T)
(inversely proportional)
P₁V₁ = P₂V₂

25
Q

Charles law
(proportionality?)

A

V and T are related
(at constant P)
(directly proportional)
V₁ / T₁ = V₂ / T₂

26
Q

Avogadros law
(proportionality?)

A

V and n are related
(at constant T and P)
(directly proportional)
V₁ / n₁ = V₂ / n₂

27
Q

Daltons law

A

Pₜ = P₁ + P₂ + P₃

28
Q

what units of temperature are needed to use the gas laws

A

Kelvin

29
Q

Ideal gas law equation

A

PV = nRT
units = atm, L, mol, K

30
Q

what are the assumptions for the ideal gas law

A
  1. Molecules have no volume
    (due to the molecules being so far apart)
  2. Molecules do not interact with each other
31
Q

STP

A

Standard Temperature and Pressure
T = 0°C
P = 1 atm

32
Q

STP vs standard state conditions

A

STP is for gas law equations, standard state conditions are for thermodynamics equations

33
Q

Molar volume (volume occupied by 1 mole of any gas at STP)

A

22.4 L

34
Q

Kinetic molecular theory of gasses

A

the theory of moving molecules

theory states:
1. molecules have no volume
2. the average KE of a molecule is proportional to its T (in K)

35
Q

how does molecular speed, temperature and energy apply to KMT

A

if speed is high, KE is high
if T is high, KE is high

36
Q

Diffusion

A

random movement of molecules to spread out and fill space

37
Q

q (equation) =

A

c * m * ΔT

38
Q

ΔH (in relation to q)=

A

q/mol

39
Q

ΔH = ΔH(products) - ΔH(reactants)

A
40
Q

KE =

A

1/2 * m * v^2

41
Q

what makes a gas a real gas

A

high P
low T

42
Q

Assumptions for the ideal gas law

A
  1. molecules have no volume
  2. molecules do not interact with each other
43
Q

what is the unit of heat needed to raise 1 g of a substance 1° C

A

specific heat capacity